23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–

Andrew J Sutherland, Olga Efremova, Michael A. Shestopalov, Natalya A. Vorotnikova, Yuri A. Vorotnikov, Yuri V. Mironov, Noboru Kitamura, Igor N. Novozhilov, Mikhail Syrokvashin, Vladimir Nadolinny, Natalia Kuratieva, David Benoit, Rochard Walton, Guy Clarkson

Research output: Contribution to journalArticle

Abstract

Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.
Original languageEnglish
Pages (from-to)811-820
JournalInorganic Chemistry
Volume57
Issue number2
Early online date22 Dec 2017
DOIs
Publication statusPublished - 31 Jan 2018

Bibliographical note

This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy.
In: Inorganic Chemistry, 11.12.2017.], copyright © American Chemical Society after peer review and technical editing by the publisher.

Funding:Russian Foundation for Basic Research (grant no. 17-03-00140) and by the Grant of the President of the Russian Federation [grant no. MK 180.2017.3], EPSRC grant EP/R006393/1

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    Sutherland, A. J., Efremova, O., Shestopalov, M. A., Vorotnikova, N. A., Vorotnikov, Y. A., Mironov, Y. V., Kitamura, N., Novozhilov, I. N., Syrokvashin, M., Nadolinny, V., Kuratieva, N., Benoit, D., Walton, R., & Clarkson, G. (2018). 23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. Inorganic Chemistry, 57(2), 811-820. https://doi.org/10.1021/acs.inorgchem.7b02760