23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–

Andrew J Sutherland, Olga Efremova, Michael A. Shestopalov, Natalya A. Vorotnikova, Yuri A. Vorotnikov, Yuri V. Mironov, Noboru Kitamura, Igor N. Novozhilov, Mikhail Syrokvashin, Vladimir Nadolinny, Natalia Kuratieva, David Benoit, Rochard Walton, Guy Clarkson

Research output: Contribution to journalArticle

Abstract

Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.
LanguageEnglish
JournalInorganic Chemistry
Early online date22 Dec 2017
DOIs
Publication statusE-pub ahead of print - 22 Dec 2017

Fingerprint

Molybdenum
molybdenum
Transition metal compounds
Electrons
Redox reactions
Electrochemical properties
Optoelectronic devices
Catalysis
Electronic structure
Magnetic properties
electrons
metal compounds
Optical properties
Crystal structure
Temperature
catalysis
transition metals
electronic structure
magnetic properties
optical properties

Bibliographical note

This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy.
In: Inorganic Chemistry, 11.12.2017.], copyright © American Chemical Society after peer review and technical editing by the publisher.

Funding:Russian Foundation for Basic Research (grant no. 17-03-00140) and by the Grant of the President of the Russian Federation [grant no. MK 180.2017.3], EPSRC grant EP/R006393/1

Cite this

Sutherland, A. J., Efremova, O., Shestopalov, M. A., Vorotnikova, N. A., Vorotnikov, Y. A., Mironov, Y. V., ... Clarkson, G. (2017). 23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.7b02760
Sutherland, Andrew J ; Efremova, Olga ; Shestopalov, Michael A. ; Vorotnikova, Natalya A. ; Vorotnikov, Yuri A. ; Mironov, Yuri V. ; Kitamura, Noboru ; Novozhilov, Igor N. ; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard ; Clarkson, Guy. / 23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. In: Inorganic Chemistry. 2017.
@article{1fccfea0efbe4d93921d48107c49c4d6,
title = "23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–",
abstract = "Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.",
author = "Sutherland, {Andrew J} and Olga Efremova and Shestopalov, {Michael A.} and Vorotnikova, {Natalya A.} and Vorotnikov, {Yuri A.} and Mironov, {Yuri V.} and Noboru Kitamura and Novozhilov, {Igor N.} and Mikhail Syrokvashin and Vladimir Nadolinny and Natalia Kuratieva and David Benoit and Rochard Walton and Guy Clarkson",
note = "This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy. In: Inorganic Chemistry, 11.12.2017.], copyright {\circledC} American Chemical Society after peer review and technical editing by the publisher. Funding:Russian Foundation for Basic Research (grant no. 17-03-00140) and by the Grant of the President of the Russian Federation [grant no. MK 180.2017.3], EPSRC grant EP/R006393/1",
year = "2017",
month = "12",
day = "22",
doi = "10.1021/acs.inorgchem.7b02760",
language = "English",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",

}

Sutherland, AJ, Efremova, O, Shestopalov, MA, Vorotnikova, NA, Vorotnikov, YA, Mironov, YV, Kitamura, N, Novozhilov, IN, Syrokvashin, M, Nadolinny, V, Kuratieva, N, Benoit, D, Walton, R & Clarkson, G 2017, '23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–' Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.7b02760

23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy.

In: Inorganic Chemistry, 22.12.2017.

Research output: Contribution to journalArticle

TY - JOUR

T1 - 23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–

AU - Sutherland, Andrew J

AU - Efremova, Olga

AU - Shestopalov, Michael A.

AU - Vorotnikova, Natalya A.

AU - Vorotnikov, Yuri A.

AU - Mironov, Yuri V.

AU - Kitamura, Noboru

AU - Novozhilov, Igor N.

AU - Syrokvashin, Mikhail

AU - Nadolinny, Vladimir

AU - Kuratieva, Natalia

AU - Benoit, David

AU - Walton, Rochard

AU - Clarkson, Guy

N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy. In: Inorganic Chemistry, 11.12.2017.], copyright © American Chemical Society after peer review and technical editing by the publisher. Funding:Russian Foundation for Basic Research (grant no. 17-03-00140) and by the Grant of the President of the Russian Federation [grant no. MK 180.2017.3], EPSRC grant EP/R006393/1

PY - 2017/12/22

Y1 - 2017/12/22

N2 - Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.

AB - Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.

U2 - 10.1021/acs.inorgchem.7b02760

DO - 10.1021/acs.inorgchem.7b02760

M3 - Article

JO - Inorganic Chemistry

T2 - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

ER -

Sutherland AJ, Efremova O, Shestopalov MA, Vorotnikova NA, Vorotnikov YA, Mironov YV et al. 23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. Inorganic Chemistry. 2017 Dec 22. https://doi.org/10.1021/acs.inorgchem.7b02760