23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–

Andrew J Sutherland; Olga Efremova; Michael A. Shestopalov; Natalya A. Vorotnikova; Yuri A. Vorotnikov; Yuri V. Mironov; Noboru Kitamura; Igor N. Novozhilov; Mikhail  Syrokvashin; Vladimir  Nadolinny; Natalia  Kuratieva; David  Benoit; Rochard Walton; Guy Clarkson

doi:10.1021/acs.inorgchem.7b02760

23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–

Andrew J Sutherland
, Olga Efremova
, Michael A. Shestopalov
, Natalya A. Vorotnikova
, Yuri A. Vorotnikov
, Yuri V. Mironov
, Noboru Kitamura
, Igor N. Novozhilov
, Mikhail Syrokvashin
, Vladimir Nadolinny
, Natalia Kuratieva
, David Benoit
, Rochard Walton
, Guy Clarkson

Chemical Engineering & Applied Chemistry

Nikolaev Institute of Inorganic Chemistry SB RAS
Department of Physics and Mathematics; University of Hull; Cottingham road HU67RX Kingston upon Hull United Kingdom
department of chemistry, University of Warwick
Novosibirsk State University
Scientific Institute of Clinical and Experimental Lymphology
Research Institute of Experimental and Clinical Medicine
Hokkaido University

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

140 Downloads (Pure)

Abstract

Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.

Original language	English
Pages (from-to)	811-820
Journal	Inorganic Chemistry
Volume	57
Issue number	2
Early online date	22 Dec 2017
DOIs	https://doi.org/10.1021/acs.inorgchem.7b02760
Publication status	Published - 31 Jan 2018

Bibliographical note

This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy.
In: Inorganic Chemistry, 11.12.2017.], copyright © American Chemical Society after peer review and technical editing by the publisher.

Funding:Russian Foundation for Basic Research (grant no. 17-03-00140) and by the Grant of the President of the Russian Federation [grant no. MK 180.2017.3], EPSRC grant EP/R006393/1

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10.1021/acs.inorgchem.7b02760

23-electron octahedral molybdenum cluster complex
This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy. In: Inorganic Chemistry, 11.12.2017.], copyright © American Chemical Society after peer review and technical editing by the publisher.
Accepted author manuscript, 1.28 MBLicence: CC BY-NC 3.0

Cite this

Sutherland, A. J., Efremova, O., Shestopalov, M. A., Vorotnikova, N. A., Vorotnikov, Y. A., Mironov, Y. V., Kitamura, N., Novozhilov, I. N., Syrokvashin, M., Nadolinny, V., Kuratieva, N., Benoit, D., Walton, R., & Clarkson, G. (2018). 23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. Inorganic Chemistry, 57(2), 811-820. https://doi.org/10.1021/acs.inorgchem.7b02760

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title = "23-electron octahedral molybdenum cluster complex [\{Mo6I8\}Cl6]–",

abstract = "Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[\{Mo6I8\}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.",

author = "Sutherland, \{Andrew J\} and Olga Efremova and Shestopalov, \{Michael A.\} and Vorotnikova, \{Natalya A.\} and Vorotnikov, \{Yuri A.\} and Mironov, \{Yuri V.\} and Noboru Kitamura and Novozhilov, \{Igor N.\} and Mikhail Syrokvashin and Vladimir Nadolinny and Natalia Kuratieva and David Benoit and Rochard Walton and Guy Clarkson",

note = "This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [\{Mo6I8\}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy. In: Inorganic Chemistry, 11.12.2017.], copyright {\textcopyright} American Chemical Society after peer review and technical editing by the publisher. Funding:Russian Foundation for Basic Research (grant no. 17-03-00140) and by the Grant of the President of the Russian Federation [grant no. MK 180.2017.3], EPSRC grant EP/R006393/1",

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doi = "10.1021/acs.inorgchem.7b02760",

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Sutherland, AJ, Efremova, O, Shestopalov, MA, Vorotnikova, NA, Vorotnikov, YA, Mironov, YV, Kitamura, N, Novozhilov, IN, Syrokvashin, M, Nadolinny, V, Kuratieva, N, Benoit, D, Walton, R & Clarkson, G 2018, '23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–', Inorganic Chemistry, vol. 57, no. 2, pp. 811-820. https://doi.org/10.1021/acs.inorgchem.7b02760

TY - JOUR

T1 - 23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–

AU - Sutherland, Andrew J

AU - Efremova, Olga

AU - Shestopalov, Michael A.

AU - Vorotnikova, Natalya A.

AU - Vorotnikov, Yuri A.

AU - Mironov, Yuri V.

AU - Kitamura, Noboru

AU - Novozhilov, Igor N.

AU - Syrokvashin, Mikhail

AU - Nadolinny, Vladimir

AU - Kuratieva, Natalia

AU - Benoit, David

AU - Walton, Rochard

AU - Clarkson, Guy

N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy. In: Inorganic Chemistry, 11.12.2017.], copyright © American Chemical Society after peer review and technical editing by the publisher. Funding:Russian Foundation for Basic Research (grant no. 17-03-00140) and by the Grant of the President of the Russian Federation [grant no. MK 180.2017.3], EPSRC grant EP/R006393/1

PY - 2018/1/31

Y1 - 2018/1/31

N2 - Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.

AB - Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.

UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02760#

U2 - 10.1021/acs.inorgchem.7b02760

DO - 10.1021/acs.inorgchem.7b02760

M3 - Article

SN - 0020-1669

VL - 57

SP - 811

EP - 820

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–

Abstract

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