A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

O.A. Efremova, M.A. Shestapalov, N.A. Chirtsova, A.I. Smolentsev, Y.V. Mironov, N. Kitamura, K.A. Brylev, Andy Sutherland

Research output: Contribution to journalArticle

Abstract

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I 8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as "polymeric ligands" to immobilise the molybdenum cluster complex. This journal is

Original languageEnglish
Pages (from-to)6021-6025
Number of pages5
JournalDalton Transactions
Volume43
Issue number16
Early online date17 Jan 2014
DOIs
Publication statusPublished - 28 Apr 2014

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Bibliographical note

© The Royal Society of Chemistry 2014

Funding: Marie Curie Intra-European Fellowship (project “PolyMoRe”, no. 327440) and the Russian Foundation for Basic Research (Grants nos. 12-03-
31670 and 14-04-01816).

Supplementary information available online on the journal pages.

Cite this

Efremova, O. A., Shestapalov, M. A., Chirtsova, N. A., Smolentsev, A. I., Mironov, Y. V., Kitamura, N., Brylev, K. A., & Sutherland, A. (2014). A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials. Dalton Transactions, 43(16), 6021-6025. https://doi.org/10.1039/c3dt53126k