A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

O.A. Efremova; M.A. Shestapalov; N.A. Chirtsova; A.I. Smolentsev; Y.V. Mironov; N. Kitamura; K.A. Brylev; Andy Sutherland

doi:10.1039/c3dt53126k

A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

O.A. Efremova, M.A. Shestapalov, N.A. Chirtsova, A.I. Smolentsev, Y.V. Mironov, N. Kitamura, K.A. Brylev, Andy Sutherland

Chemical Engineering & Applied Chemistry

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Abstract

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu₄N)₂[Mo₆I ₈(NO₃)₆], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as "polymeric ligands" to immobilise the molybdenum cluster complex. This journal is

Original language	English
Pages (from-to)	6021-6025
Number of pages	5
Journal	Dalton Transactions
Volume	43
Issue number	16
Early online date	17 Jan 2014
DOIs	https://doi.org/10.1039/c3dt53126k
Publication status	Published - 28 Apr 2014

Bibliographical note

© The Royal Society of Chemistry 2014

Funding: Marie Curie Intra-European Fellowship (project “PolyMoRe”, no. 327440) and the Russian Foundation for Basic Research (Grants nos. 12-03-
31670 and 14-04-01816).

Supplementary information available online on the journal pages.

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10.1039/c3dt53126k

A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor
© The Royal Society of Chemistry 2014
Accepted author manuscript, 285 KB

https://hydra.hull.ac.uk/resources/hull:11414

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AU - Shestapalov, M.A.

AU - Chirtsova, N.A.

AU - Smolentsev, A.I.

AU - Mironov, Y.V.

AU - Kitamura, N.

AU - Brylev, K.A.

AU - Sutherland, Andy

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A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

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