A novel low-temperature fabrication approach of composite phase change materials for high temperature thermal energy storage

Qinghua Yu, Zhu Jiang, Lin Cong, Tiejun Lu, Bilyaminu Suleiman, Guanghui Leng, Zhentao Wu, Yulong Ding, Yongliang Li*

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

Phase change materials (PCMs) are generally integrated into matrix materials to form shape-stabilized composite heat storage materials (HSMs) used for high temperature thermal energy storage applications. The conventional fabrication of composite HSMs is prevalently implemented at quite high temperatures, which is energy-intensive and narrows down the range of applicable PCMs because of thermal decomposition. Therefore, this paper establishes a novel fabrication approach to accomplish highly dense matrix to encapsulate PCMs at extremely low temperatures, based on the recently developed cold sintering process. The feasibility of the proposed approach was demonstrated by a case study of NaNO3/Ca(OH)2 composite HSMs. It was observed that the Ca(OH)2 matrix formed dense microstructure with obvious sintered boundaries and successfully encapsulated NaNO3 as PCM. The HSMs maintained stable macroscopic shape after hundreds of thermal cycles, and exhibited an energy storage efficiency of 59.48%, little leakage of PCM, and good thermal stability. Mechanical tests indicated that the HSMs possessed excellent mechanical properties when the sintering pressure is over 220 MPa. The discharging time of stored heat was presented through infrared thermography, and the heat storage capacity measured for the composite HSMs was over four times as high as those of typical solid storage materials of sensible heat, which demonstrated their excellent heat storage performances. The HSMs can be used in the form of packed bed or parallel channel with multi-layered heat storage, which is beneficial for efficiently utilizing solar heat and improving the performance of current energy storage system. This study therefore provides a novel route for energy-saving and low-carbon fabrication of shape-stabilized composite HSMs.

Original languageEnglish
Pages (from-to)367-377
Number of pages11
JournalApplied Energy
Volume237
Early online date23 Jan 2019
DOIs
Publication statusPublished - 1 Mar 2019

Fingerprint

Heat storage
Phase change materials
Thermal energy
Energy storage
Fabrication
Composite materials
Temperature
material
energy storage
Sintering
matrix
heat storage
Packed beds
thermal decomposition
Energy conservation
Pyrolysis
Thermodynamic stability

Bibliographical note

© 2019, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/

Keywords

  • Cold sintering
  • Dense structure
  • Heat storage
  • Phase change material

Cite this

Yu, Qinghua ; Jiang, Zhu ; Cong, Lin ; Lu, Tiejun ; Suleiman, Bilyaminu ; Leng, Guanghui ; Wu, Zhentao ; Ding, Yulong ; Li, Yongliang. / A novel low-temperature fabrication approach of composite phase change materials for high temperature thermal energy storage. In: Applied Energy. 2019 ; Vol. 237. pp. 367-377.
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abstract = "Phase change materials (PCMs) are generally integrated into matrix materials to form shape-stabilized composite heat storage materials (HSMs) used for high temperature thermal energy storage applications. The conventional fabrication of composite HSMs is prevalently implemented at quite high temperatures, which is energy-intensive and narrows down the range of applicable PCMs because of thermal decomposition. Therefore, this paper establishes a novel fabrication approach to accomplish highly dense matrix to encapsulate PCMs at extremely low temperatures, based on the recently developed cold sintering process. The feasibility of the proposed approach was demonstrated by a case study of NaNO3/Ca(OH)2 composite HSMs. It was observed that the Ca(OH)2 matrix formed dense microstructure with obvious sintered boundaries and successfully encapsulated NaNO3 as PCM. The HSMs maintained stable macroscopic shape after hundreds of thermal cycles, and exhibited an energy storage efficiency of 59.48{\%}, little leakage of PCM, and good thermal stability. Mechanical tests indicated that the HSMs possessed excellent mechanical properties when the sintering pressure is over 220 MPa. The discharging time of stored heat was presented through infrared thermography, and the heat storage capacity measured for the composite HSMs was over four times as high as those of typical solid storage materials of sensible heat, which demonstrated their excellent heat storage performances. The HSMs can be used in the form of packed bed or parallel channel with multi-layered heat storage, which is beneficial for efficiently utilizing solar heat and improving the performance of current energy storage system. This study therefore provides a novel route for energy-saving and low-carbon fabrication of shape-stabilized composite HSMs.",
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A novel low-temperature fabrication approach of composite phase change materials for high temperature thermal energy storage. / Yu, Qinghua; Jiang, Zhu; Cong, Lin; Lu, Tiejun; Suleiman, Bilyaminu; Leng, Guanghui; Wu, Zhentao; Ding, Yulong; Li, Yongliang.

In: Applied Energy, Vol. 237, 01.03.2019, p. 367-377.

Research output: Contribution to journalArticle

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T1 - A novel low-temperature fabrication approach of composite phase change materials for high temperature thermal energy storage

AU - Yu, Qinghua

AU - Jiang, Zhu

AU - Cong, Lin

AU - Lu, Tiejun

AU - Suleiman, Bilyaminu

AU - Leng, Guanghui

AU - Wu, Zhentao

AU - Ding, Yulong

AU - Li, Yongliang

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PY - 2019/3/1

Y1 - 2019/3/1

N2 - Phase change materials (PCMs) are generally integrated into matrix materials to form shape-stabilized composite heat storage materials (HSMs) used for high temperature thermal energy storage applications. The conventional fabrication of composite HSMs is prevalently implemented at quite high temperatures, which is energy-intensive and narrows down the range of applicable PCMs because of thermal decomposition. Therefore, this paper establishes a novel fabrication approach to accomplish highly dense matrix to encapsulate PCMs at extremely low temperatures, based on the recently developed cold sintering process. The feasibility of the proposed approach was demonstrated by a case study of NaNO3/Ca(OH)2 composite HSMs. It was observed that the Ca(OH)2 matrix formed dense microstructure with obvious sintered boundaries and successfully encapsulated NaNO3 as PCM. The HSMs maintained stable macroscopic shape after hundreds of thermal cycles, and exhibited an energy storage efficiency of 59.48%, little leakage of PCM, and good thermal stability. Mechanical tests indicated that the HSMs possessed excellent mechanical properties when the sintering pressure is over 220 MPa. The discharging time of stored heat was presented through infrared thermography, and the heat storage capacity measured for the composite HSMs was over four times as high as those of typical solid storage materials of sensible heat, which demonstrated their excellent heat storage performances. The HSMs can be used in the form of packed bed or parallel channel with multi-layered heat storage, which is beneficial for efficiently utilizing solar heat and improving the performance of current energy storage system. This study therefore provides a novel route for energy-saving and low-carbon fabrication of shape-stabilized composite HSMs.

AB - Phase change materials (PCMs) are generally integrated into matrix materials to form shape-stabilized composite heat storage materials (HSMs) used for high temperature thermal energy storage applications. The conventional fabrication of composite HSMs is prevalently implemented at quite high temperatures, which is energy-intensive and narrows down the range of applicable PCMs because of thermal decomposition. Therefore, this paper establishes a novel fabrication approach to accomplish highly dense matrix to encapsulate PCMs at extremely low temperatures, based on the recently developed cold sintering process. The feasibility of the proposed approach was demonstrated by a case study of NaNO3/Ca(OH)2 composite HSMs. It was observed that the Ca(OH)2 matrix formed dense microstructure with obvious sintered boundaries and successfully encapsulated NaNO3 as PCM. The HSMs maintained stable macroscopic shape after hundreds of thermal cycles, and exhibited an energy storage efficiency of 59.48%, little leakage of PCM, and good thermal stability. Mechanical tests indicated that the HSMs possessed excellent mechanical properties when the sintering pressure is over 220 MPa. The discharging time of stored heat was presented through infrared thermography, and the heat storage capacity measured for the composite HSMs was over four times as high as those of typical solid storage materials of sensible heat, which demonstrated their excellent heat storage performances. The HSMs can be used in the form of packed bed or parallel channel with multi-layered heat storage, which is beneficial for efficiently utilizing solar heat and improving the performance of current energy storage system. This study therefore provides a novel route for energy-saving and low-carbon fabrication of shape-stabilized composite HSMs.

KW - Cold sintering

KW - Dense structure

KW - Heat storage

KW - Phase change material

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