Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint

L.P.N. Rebelo, J.N. Canongia Lopes, J.M.S.S. Esperança, H.J.R. Guedes, J. Łachwa, V. Najdanovic-Visak, Z.P. Visak

Research output: Contribution to journalArticlepeer-review

Abstract

The fascinating, complex behavior of ionic liquids is analyzed using a molecular perspective that emphasizes the doubly dual nature of ionic liquids underlying the existence of cations and anions forming high- and low-charge-density regions. Our work bridges the liquid, gas, and solid phases spanning 5 years of research on themes as diverse as the vaporization, liquid–liquid demixing, solidification, and thermophysical behavior of ionic liquids and their mixtures and solutions.
Original languageEnglish
Pages (from-to)1114-1121
JournalAccounts of Chemical Research
Volume40
Issue number11
DOIs
Publication statusPublished - 11 Jul 2007

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