Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint

L.P.N. Rebelo, J.N. Canongia Lopes, J.M.S.S. Esperança, H.J.R. Guedes, J. Łachwa, V. Najdanovic-Visak, Z.P. Visak

Research output: Contribution to journalArticle

Abstract

The fascinating, complex behavior of ionic liquids is analyzed using a molecular perspective that emphasizes the doubly dual nature of ionic liquids underlying the existence of cations and anions forming high- and low-charge-density regions. Our work bridges the liquid, gas, and solid phases spanning 5 years of research on themes as diverse as the vaporization, liquid–liquid demixing, solidification, and thermophysical behavior of ionic liquids and their mixtures and solutions.
Original languageEnglish
Pages (from-to)1114-1121
JournalAccounts of Chemical Research
Volume40
Issue number11
DOIs
Publication statusPublished - 11 Jul 2007

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Ionic Liquids
Thermodynamics
Charge density
Vaporization
Anions
Solidification
Cations
Gases
Liquids

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Rebelo, L. P. N., Canongia Lopes, J. N., Esperança, J. M. S. S., Guedes, H. J. R., Łachwa, J., Najdanovic-Visak, V., & Visak, Z. P. (2007). Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint. Accounts of Chemical Research, 40(11), 1114-1121. https://doi.org/10.1021/ar7000556
Rebelo, L.P.N. ; Canongia Lopes, J.N. ; Esperança, J.M.S.S. ; Guedes, H.J.R. ; Łachwa, J. ; Najdanovic-Visak, V. ; Visak, Z.P. / Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint. In: Accounts of Chemical Research. 2007 ; Vol. 40, No. 11. pp. 1114-1121.
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Rebelo, LPN, Canongia Lopes, JN, Esperança, JMSS, Guedes, HJR, Łachwa, J, Najdanovic-Visak, V & Visak, ZP 2007, 'Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint', Accounts of Chemical Research, vol. 40, no. 11, pp. 1114-1121. https://doi.org/10.1021/ar7000556

Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint. / Rebelo, L.P.N.; Canongia Lopes, J.N.; Esperança, J.M.S.S.; Guedes, H.J.R.; Łachwa, J.; Najdanovic-Visak, V.; Visak, Z.P.

In: Accounts of Chemical Research, Vol. 40, No. 11, 11.07.2007, p. 1114-1121.

Research output: Contribution to journalArticle

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Rebelo LPN, Canongia Lopes JN, Esperança JMSS, Guedes HJR, Łachwa J, Najdanovic-Visak V et al. Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint. Accounts of Chemical Research. 2007 Jul 11;40(11):1114-1121. https://doi.org/10.1021/ar7000556