Alkali-Free Zn–Al Layered Double Hydroxide Catalysts for Triglyceride Transesterification

Nazrizawati Tajuddin, Jinesh Manayil, Mark Isaacs, Christopher Parlett, Adam Lee, Karen Wilson

Research output: Contribution to journalArticle

Abstract

Zn–Al layered double hydroxides (LDHs) of general formula [Zn2+(1−x)Al3+x(OH)2]x+(CO32−)x/2·yH2O are promising solid base catalysts for the transesterification of lipids to biofuels. However, conventional synthetic routes employ alkali hydroxide/carbonate precipitants which may contaminate the final LDH catalyst and biofuel. The use of (NH3)2CO3 and NH3OH as precipitants affords alkali-free Zn–Al-LDHs spanning a wide composition range. The hydrothermal reconstruction of calcined Zn–Al-LDHs offers superior solid basicity and catalytic activity for the transesterification of C4–C18 triglycerides with methanol, compared with cold liquid phase or vapour phase reconstruction. Hydrothermally activated Zn3.3–Al-LDH was stable towards leaching during transesterification.
Original languageEnglish
Article number667
JournalCatalysts
Volume8
Issue number12
DOIs
Publication statusPublished - 18 Dec 2018

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Hydroxides
Transesterification
Alkalies
hydroxides
alkalies
Triglycerides
Biofuels
catalysts
Catalysts
Alkalinity
Lipids
Leaching
Carbonates
Catalyst activity
Methanol
Vapors
Liquids
leaching
Chemical analysis
lipids

Bibliographical note

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

Cite this

Tajuddin, Nazrizawati ; Manayil, Jinesh ; Isaacs, Mark ; Parlett, Christopher ; Lee, Adam ; Wilson, Karen. / Alkali-Free Zn–Al Layered Double Hydroxide Catalysts for Triglyceride Transesterification. In: Catalysts. 2018 ; Vol. 8, No. 12.
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abstract = "Zn–Al layered double hydroxides (LDHs) of general formula [Zn2+(1−x)Al3+x(OH)2]x+(CO32−)x/2·yH2O are promising solid base catalysts for the transesterification of lipids to biofuels. However, conventional synthetic routes employ alkali hydroxide/carbonate precipitants which may contaminate the final LDH catalyst and biofuel. The use of (NH3)2CO3 and NH3OH as precipitants affords alkali-free Zn–Al-LDHs spanning a wide composition range. The hydrothermal reconstruction of calcined Zn–Al-LDHs offers superior solid basicity and catalytic activity for the transesterification of C4–C18 triglycerides with methanol, compared with cold liquid phase or vapour phase reconstruction. Hydrothermally activated Zn3.3–Al-LDH was stable towards leaching during transesterification.",
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Alkali-Free Zn–Al Layered Double Hydroxide Catalysts for Triglyceride Transesterification. / Tajuddin, Nazrizawati; Manayil, Jinesh; Isaacs, Mark; Parlett, Christopher; Lee, Adam; Wilson, Karen.

In: Catalysts, Vol. 8, No. 12, 667, 18.12.2018.

Research output: Contribution to journalArticle

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AU - Lee, Adam

AU - Wilson, Karen

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