Biocompatible choline based ionic salts: Solubility in short-chain alcohols

J.M. Lopes; A.B. Paninho; M.F. Môlho; A.V.M. Nunes; A. Rocha; N.M.T. Lourenço; V. Najdanovic-Visak

doi:10.1016/j.jct.2013.07.025

Biocompatible choline based ionic salts: Solubility in short-chain alcohols

J.M. Lopes
, A.B. Paninho
, M.F. Môlho
, A.V.M. Nunes
, A. Rocha
, N.M.T. Lourenço
, V. Najdanovic-Visak

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

In this work, we report data on solubility of choline chloride and choline acetate in short-chain linear alcohols (ethanol, 1-propanol and 1-butanol) at various temperatures. Furthermore, we synthesize two choline derivatives: hydrogen choline chloride glutarate ([CholGlut][Cl]) and hydrogen choline chloride succinate ([CholSucc][Cl]). Their characterization and solubility in short-chain alcohols as a function of temperature are also included. Activity coefficients were calculated and their comparisons with ideal solutions were discussed. The experimental data were correlated successfully by means of the semi-empirical Grant equation.

Original language	English
Pages (from-to)	99-105
Journal	Journal of Chemical Thermodynamics
Volume	67
DOIs	https://doi.org/10.1016/j.jct.2013.07.025
Publication status	Published - 1 Dec 2013

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10.1016/j.jct.2013.07.025

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title = "Biocompatible choline based ionic salts: Solubility in short-chain alcohols",

abstract = "In this work, we report data on solubility of choline chloride and choline acetate in short-chain linear alcohols (ethanol, 1-propanol and 1-butanol) at various temperatures. Furthermore, we synthesize two choline derivatives: hydrogen choline chloride glutarate ([CholGlut][Cl]) and hydrogen choline chloride succinate ([CholSucc][Cl]). Their characterization and solubility in short-chain alcohols as a function of temperature are also included. Activity coefficients were calculated and their comparisons with ideal solutions were discussed. The experimental data were correlated successfully by means of the semi-empirical Grant equation.",

author = "J.M. Lopes and A.B. Paninho and M.F. M{\^o}lho and A.V.M. Nunes and A. Rocha and N.M.T. Louren{\c c}o and V. Najdanovic-Visak",

year = "2013",

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doi = "10.1016/j.jct.2013.07.025",

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T1 - Biocompatible choline based ionic salts: Solubility in short-chain alcohols

AU - Lopes, J.M.

AU - Paninho, A.B.

AU - Môlho, M.F.

AU - Nunes, A.V.M.

AU - Rocha, A.

AU - Lourenço, N.M.T.

AU - Najdanovic-Visak, V.

PY - 2013/12/1

Y1 - 2013/12/1

N2 - In this work, we report data on solubility of choline chloride and choline acetate in short-chain linear alcohols (ethanol, 1-propanol and 1-butanol) at various temperatures. Furthermore, we synthesize two choline derivatives: hydrogen choline chloride glutarate ([CholGlut][Cl]) and hydrogen choline chloride succinate ([CholSucc][Cl]). Their characterization and solubility in short-chain alcohols as a function of temperature are also included. Activity coefficients were calculated and their comparisons with ideal solutions were discussed. The experimental data were correlated successfully by means of the semi-empirical Grant equation.

AB - In this work, we report data on solubility of choline chloride and choline acetate in short-chain linear alcohols (ethanol, 1-propanol and 1-butanol) at various temperatures. Furthermore, we synthesize two choline derivatives: hydrogen choline chloride glutarate ([CholGlut][Cl]) and hydrogen choline chloride succinate ([CholSucc][Cl]). Their characterization and solubility in short-chain alcohols as a function of temperature are also included. Activity coefficients were calculated and their comparisons with ideal solutions were discussed. The experimental data were correlated successfully by means of the semi-empirical Grant equation.

UR - https://www.scopus.com/pages/publications/84883514922

UR - https://www.sciencedirect.com/science/article/pii/S0021961413002735?via%3Dihub

U2 - 10.1016/j.jct.2013.07.025

DO - 10.1016/j.jct.2013.07.025

M3 - Article

SN - 0021-9614

VL - 67

SP - 99

EP - 105

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

ER -

Biocompatible choline based ionic salts: Solubility in short-chain alcohols

Abstract

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