Chiral and chemical oscillations in a simple dimerization model

Michael Stich; Celia Blanco; David Hochberg

doi:10.1039/c2cp42620j

Chiral and chemical oscillations in a simple dimerization model

Michael Stich^*, Celia Blanco, David Hochberg

^*Corresponding author for this work

Mathematics

Research output: Contribution to journal › Article › peer-review

Abstract

We consider the APED model (activation-polymerization-epimerization- depolymerization) for describing the emergence of chiral solutions within a non-catalytic framework for chiral polymerization. The minimal APED model for dimerization can lead to the spontaneous appearance of chiral oscillations and we describe in detail the nature of these oscillations in the enantiomeric excess, which are the consequence of oscillations of the concentrations of the associated chemical species.

Original language	English
Pages (from-to)	255-261
Number of pages	7
Journal	Physical Chemistry Chemical Physics
Volume	15
Issue number	1
Early online date	19 Sept 2012
DOIs	https://doi.org/10.1039/c2cp42620j
Publication status	Published - 7 Jan 2013

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10.1039/c2cp42620j

Chiral and chemical oscillations in a simple dimerization model
© The Royal Society of Chemistry 2012
Accepted author manuscript, 439 KB

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abstract = "We consider the APED model (activation-polymerization-epimerization- depolymerization) for describing the emergence of chiral solutions within a non-catalytic framework for chiral polymerization. The minimal APED model for dimerization can lead to the spontaneous appearance of chiral oscillations and we describe in detail the nature of these oscillations in the enantiomeric excess, which are the consequence of oscillations of the concentrations of the associated chemical species.",

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AB - We consider the APED model (activation-polymerization-epimerization- depolymerization) for describing the emergence of chiral solutions within a non-catalytic framework for chiral polymerization. The minimal APED model for dimerization can lead to the spontaneous appearance of chiral oscillations and we describe in detail the nature of these oscillations in the enantiomeric excess, which are the consequence of oscillations of the concentrations of the associated chemical species.

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Chiral and chemical oscillations in a simple dimerization model

Abstract

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