Chiral and chemical oscillations in a simple dimerization model

Michael Stich; Celia Blanco; David Hochberg

doi:10.1039/c2cp42620j

Chiral and chemical oscillations in a simple dimerization model

Michael Stich^*
, Celia Blanco
, David Hochberg

^*Corresponding author for this work

Instituto Nacional de Técnica Aeroespacial

Research output: Contribution to journal › Article › peer-review

15 Citations (SciVal)

51 Downloads (Pure)

Abstract

We consider the APED model (activation-polymerization-epimerization- depolymerization) for describing the emergence of chiral solutions within a non-catalytic framework for chiral polymerization. The minimal APED model for dimerization can lead to the spontaneous appearance of chiral oscillations and we describe in detail the nature of these oscillations in the enantiomeric excess, which are the consequence of oscillations of the concentrations of the associated chemical species.

Original language	English
Pages (from-to)	255-261
Number of pages	7
Journal	Physical Chemistry Chemical Physics
Volume	15
Issue number	1
Early online date	19 Sept 2012
DOIs	https://doi.org/10.1039/c2cp42620j
Publication status	Published - 7 Jan 2013

Bibliographical note

Access to Document

10.1039/c2cp42620j

Chiral and chemical oscillations in a simple dimerization model
© The Royal Society of Chemistry 2012
Accepted author manuscript, 439 KB

Cite this

@article{3c49a5fbd47b449ab30e8eb20c3cea89,

title = "Chiral and chemical oscillations in a simple dimerization model",

abstract = "We consider the APED model (activation-polymerization-epimerization- depolymerization) for describing the emergence of chiral solutions within a non-catalytic framework for chiral polymerization. The minimal APED model for dimerization can lead to the spontaneous appearance of chiral oscillations and we describe in detail the nature of these oscillations in the enantiomeric excess, which are the consequence of oscillations of the concentrations of the associated chemical species.",

author = "Michael Stich and Celia Blanco and David Hochberg",

note = "{\textcopyright} The Royal Society of Chemistry 2012 ",

year = "2013",

month = jan,

day = "7",

doi = "10.1039/c2cp42620j",

language = "English",

volume = "15",

pages = "255--261",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Chiral and chemical oscillations in a simple dimerization model

AU - Stich, Michael

AU - Blanco, Celia

AU - Hochberg, David

N1 - © The Royal Society of Chemistry 2012

PY - 2013/1/7

Y1 - 2013/1/7

N2 - We consider the APED model (activation-polymerization-epimerization- depolymerization) for describing the emergence of chiral solutions within a non-catalytic framework for chiral polymerization. The minimal APED model for dimerization can lead to the spontaneous appearance of chiral oscillations and we describe in detail the nature of these oscillations in the enantiomeric excess, which are the consequence of oscillations of the concentrations of the associated chemical species.

AB - We consider the APED model (activation-polymerization-epimerization- depolymerization) for describing the emergence of chiral solutions within a non-catalytic framework for chiral polymerization. The minimal APED model for dimerization can lead to the spontaneous appearance of chiral oscillations and we describe in detail the nature of these oscillations in the enantiomeric excess, which are the consequence of oscillations of the concentrations of the associated chemical species.

UR - http://pubs.rsc.org/en/Content/ArticleLanding/2013/CP/C2CP42620J#!divAbstract

UR - https://www.scopus.com/pages/publications/84870863858

U2 - 10.1039/c2cp42620j

DO - 10.1039/c2cp42620j

M3 - Article

C2 - 23064600

AN - SCOPUS:84870863858

SN - 1463-9076

VL - 15

SP - 255

EP - 261

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 1

ER -

Chiral and chemical oscillations in a simple dimerization model

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this