TY - JOUR
T1 - Crystal structure and physical properties of the new linear chain compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2
AU - van Koningsbruggen, Petra J.
AU - Garcia, Yann
AU - Bravic, Georges
AU - Chasseau, Daniel
AU - Kahn, Olivier
N1 - Copyright 2007 Elsevier B.V., All rights reserved.
PY - 2001/12/17
Y1 - 2001/12/17
N2 - The synthesis and crystal structure of a novel one-dimensional Cu(II) compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2 are described. The single-crystal X-ray structure determination was carried out at 298 K. The molecular structure consists of a linear chain in which the Cu(II) ions are linked by three N4,N4′ coordinating bis(tetrazole) ligands in syn conformation. The Cu(II) ions are in a Jahn–Teller distorted octahedral environment (Cu(1)N(11)=2.034(2) Å, Cu(1)N(21)=2.041(2) Å and Cu(1)N(31)=2.391(2) Å). The Cu⋯Cu separations are 7.420(3) Å.The synthesis and crystal structure of a novel 1-D Cu(II) compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2 are described. The single-crystal X-ray structure determination was carried out at 298 K. The molecular structure consists of a linear chain in which the Cu(II) ions are linked by three N4,N4′ coordinating bis(tetrazole) ligands in syn conformation. The Cu⋯Cu separations are 7.420(3) Å.
AB - The synthesis and crystal structure of a novel one-dimensional Cu(II) compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2 are described. The single-crystal X-ray structure determination was carried out at 298 K. The molecular structure consists of a linear chain in which the Cu(II) ions are linked by three N4,N4′ coordinating bis(tetrazole) ligands in syn conformation. The Cu(II) ions are in a Jahn–Teller distorted octahedral environment (Cu(1)N(11)=2.034(2) Å, Cu(1)N(21)=2.041(2) Å and Cu(1)N(31)=2.391(2) Å). The Cu⋯Cu separations are 7.420(3) Å.The synthesis and crystal structure of a novel 1-D Cu(II) compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2 are described. The single-crystal X-ray structure determination was carried out at 298 K. The molecular structure consists of a linear chain in which the Cu(II) ions are linked by three N4,N4′ coordinating bis(tetrazole) ligands in syn conformation. The Cu⋯Cu separations are 7.420(3) Å.
KW - copper
KW - chain structures
KW - supramolecular chemistry
UR - http://www.scopus.com/inward/record.url?scp=0035904980&partnerID=8YFLogxK
UR - https://www.sciencedirect.com/science/article/pii/S0020169301006454?via%3Dihub
U2 - 10.1016/S0020-1693(01)00645-4
DO - 10.1016/S0020-1693(01)00645-4
M3 - Article
AN - SCOPUS:0035904980
SN - 0020-1693
VL - 326
SP - 101
EP - 105
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -