Crystal structure and physical properties of the new linear chain compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2

Petra J. van Koningsbruggen, Yann Garcia, Georges Bravic, Daniel Chasseau, Olivier Kahn

Research output: Contribution to journalArticle

Abstract

The synthesis and crystal structure of a novel one-dimensional Cu(II) compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2 are described. The single-crystal X-ray structure determination was carried out at 298 K. The molecular structure consists of a linear chain in which the Cu(II) ions are linked by three N4,N4′ coordinating bis(tetrazole) ligands in syn conformation. The Cu(II) ions are in a Jahn–Teller distorted octahedral environment (Cu(1)N(11)=2.034(2) Å, Cu(1)N(21)=2.041(2) Å and Cu(1)N(31)=2.391(2) Å). The Cu⋯Cu separations are 7.420(3) Å.

The synthesis and crystal structure of a novel 1-D Cu(II) compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2 are described. The single-crystal X-ray structure determination was carried out at 298 K. The molecular structure consists of a linear chain in which the Cu(II) ions are linked by three N4,N4′ coordinating bis(tetrazole) ligands in syn conformation. The Cu⋯Cu separations are 7.420(3) Å.

Original languageEnglish
Pages (from-to)101-105
Number of pages5
JournalInorganica Chimica Acta
Volume326
Issue number1
Early online date27 Nov 2001
DOIs
Publication statusPublished - 17 Dec 2001

Keywords

  • copper
  • chain structures
  • supramolecular chemistry

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