Crystal structure of [{Cu(H2O)(en)2}{Cu(en)2}Re6Te8(CN)6]·3H2O

Yu V. Mironov, O.A. Efremova, V.E. Fedorov

Research output: Contribution to journalArticle

Abstract

The reaction of Cs4[Re6Te8(CN)6]·2H2O with Cu(en)2Cl2 in water affords crystals of a cluster complex [{Cu(H2O)(en) 2}{Cu(en)2}Re6Te8(CN)6]·3H2O. The structure of the compound is determined by single crystal X-ray diffraction (a = 10.8082(4) Å, b = 16.5404(6) Å, c = 24.6480(7) Å, β = 92.696(1)°, V = 4401.5(3) Å3, Z = 4, space group P21/n, R 1 = 0.0331, wR 2 (all data) = 0.0652). In the complex, cluster [Re6Te8(CN)6]4- anions are linked by Cu2+ cations into zigzag chains through cyanide bridges. The coordination environment of the copper cations is complemented by ethylenediamine molecules. Each of the cluster anions is additionally coordinated by a terminal fragment {Cu(H2O)(en)2}.

Original languageEnglish
Pages (from-to)360-362
Number of pages3
JournalJournal of Structural Chemistry
Volume55
Issue number2
DOIs
Publication statusPublished - 1 Mar 2014

Keywords

  • chalcocyanide complex
  • crystal structure
  • octahedral cluster
  • rhenium
  • synthesis

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