TY - JOUR
T1 - Cyclic carbonate synthesis from CO2and epoxides using zinc(II) complexes of arylhydrazones of β-diketones
AU - Montoya, C.A.
AU - Gómez, C.F.
AU - Paninho, A.B.
AU - Nunes, A.V.M.
AU - Mahmudov, K.T.
AU - Najdanovic-Visak, V.
AU - Martins, L.M.D.R.S.
AU - Guedes Da Silva, M.F.C.
AU - Pombeiro, A.J.L.
AU - Nunes Da Ponte, M.
N1 - © 2016, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
PY - 2016/3/1
Y1 - 2016/3/1
N2 - Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.
AB - Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.
UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-84955087154&partnerID=MN8TOARS
UR - https://www.sciencedirect.com/science/article/pii/S002195171600004X?via%3Dihub
U2 - 10.1016/j.jcat.2015.12.027
DO - 10.1016/j.jcat.2015.12.027
M3 - Article
SN - 0021-9517
VL - 335
SP - 135
EP - 140
JO - Journal of Catalysis
JF - Journal of Catalysis
ER -