Cyclic carbonate synthesis from CO2and epoxides using zinc(II) complexes of arylhydrazones of β-diketones

C.A. Montoya; C.F. Gómez; A.B. Paninho; A.V.M. Nunes; K.T. Mahmudov; V. Najdanovic-Visak; L.M.D.R.S. Martins; M.F.C. Guedes Da Silva; A.J.L. Pombeiro; M. Nunes Da Ponte

doi:10.1016/j.jcat.2015.12.027

Cyclic carbonate synthesis from CO2and epoxides using zinc(II) complexes of arylhydrazones of β-diketones

C.A. Montoya
, C.F. Gómez
, A.B. Paninho
, A.V.M. Nunes
, K.T. Mahmudov
, V. Najdanovic-Visak
, L.M.D.R.S. Martins
, M.F.C. Guedes Da Silva
, A.J.L. Pombeiro
, M. Nunes Da Ponte

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

59 Downloads (Pure)

Abstract

Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.

Original language	English
Pages (from-to)	135-140
Journal	Journal of Catalysis
Volume	335
DOIs	https://doi.org/10.1016/j.jcat.2015.12.027
Publication status	Published - 1 Mar 2016

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10.1016/j.jcat.2015.12.027

Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes
© 2016, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Accepted author manuscript, 296 KBLicence: CC BY-NC-ND 3.0

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Montoya, C. A., Gómez, C. F., Paninho, A. B., Nunes, A. V. M., Mahmudov, K. T., Najdanovic-Visak, V., Martins, L. M. D. R. S., Guedes Da Silva, M. F. C., Pombeiro, A. J. L., & Nunes Da Ponte, M. (2016). Cyclic carbonate synthesis from CO2and epoxides using zinc(II) complexes of arylhydrazones of β-diketones. Journal of Catalysis, 335, 135-140. https://doi.org/10.1016/j.jcat.2015.12.027

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title = "Cyclic carbonate synthesis from CO2and epoxides using zinc(II) complexes of arylhydrazones of β-diketones",

abstract = "Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.",

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doi = "10.1016/j.jcat.2015.12.027",

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T1 - Cyclic carbonate synthesis from CO2and epoxides using zinc(II) complexes of arylhydrazones of β-diketones

AU - Montoya, C.A.

AU - Gómez, C.F.

AU - Paninho, A.B.

AU - Nunes, A.V.M.

AU - Mahmudov, K.T.

AU - Najdanovic-Visak, V.

AU - Martins, L.M.D.R.S.

AU - Guedes Da Silva, M.F.C.

AU - Pombeiro, A.J.L.

AU - Nunes Da Ponte, M.

PY - 2016/3/1

Y1 - 2016/3/1

N2 - Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.

AB - Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.

UR - https://www.scopus.com/pages/publications/84955087154

UR - https://www.sciencedirect.com/science/article/pii/S002195171600004X?via%3Dihub

U2 - 10.1016/j.jcat.2015.12.027

DO - 10.1016/j.jcat.2015.12.027

M3 - Article

SN - 0021-9517

VL - 335

SP - 135

EP - 140

JO - Journal of Catalysis

JF - Journal of Catalysis

ER -

Cyclic carbonate synthesis from CO2and epoxides using zinc(II) complexes of arylhydrazones of β-diketones

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