Electrocatalytic regeneration of atmospherically aged MoS2 nanostructures via solution-phase sulfidation

H.A. Burch, M. Isaacs, K. Wilson, R.E. Palmer, N.V. Rees

Research output: Contribution to journalArticle

Abstract

The performance of MoS2 as a hydrogen evolution catalyst is diminished by exposure to air. We demonstrate a solution phase technique to resulfidate MoSxO2-x using Na2S2O3. The success of the method was judged by performance as a H+ reduction catalyst. Following sulfidation samples displayed a favourable decrease in both onset potential and Tafel slope, with the best decreasing from -0.23 V to -0.18 V (vs. SHE), and 282 mV dec-1 to 87 mV dec-1 respectively. Ageing studies indicate that this method may be used to recycle the MoS2 repeatedly without losing catalytic performance, although repeated sulfidation did result in homogenisation of the nanostructure.

Original languageEnglish
Pages (from-to)26689-26695
Number of pages7
JournalRSC advances
Volume6
Issue number32
Early online date4 Mar 2016
DOIs
Publication statusPublished - 2016

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Nanostructures
Catalysts
Hydrogen
Aging of materials
Air

Bibliographical note

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Funding: EPSRC

Electronic supplementary information (ESI) available. See DOI: 10.1039/c6ra03326a

Cite this

Burch, H.A. ; Isaacs, M. ; Wilson, K. ; Palmer, R.E. ; Rees, N.V. / Electrocatalytic regeneration of atmospherically aged MoS2 nanostructures via solution-phase sulfidation. In: RSC advances. 2016 ; Vol. 6, No. 32. pp. 26689-26695.
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Burch, HA, Isaacs, M, Wilson, K, Palmer, RE & Rees, NV 2016, 'Electrocatalytic regeneration of atmospherically aged MoS2 nanostructures via solution-phase sulfidation', RSC advances, vol. 6, no. 32, pp. 26689-26695. https://doi.org/10.1039/c6ra03326a

Electrocatalytic regeneration of atmospherically aged MoS2 nanostructures via solution-phase sulfidation. / Burch, H.A.; Isaacs, M.; Wilson, K.; Palmer, R.E.; Rees, N.V.

In: RSC advances, Vol. 6, No. 32, 2016, p. 26689-26695.

Research output: Contribution to journalArticle

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AU - Isaacs, M.

AU - Wilson, K.

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AU - Rees, N.V.

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