Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure

Sílvia Rebocho, Ana V. M. Nunes, Vesna Najdanovic-Visak, Susana Barreiros, Alexandre Paiva

Research output: Contribution to journalArticle

Abstract

The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng–Robinson equation of state and the Mathias–Klotz–Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.
Original languageEnglish
Pages (from-to)210-213
JournalJournal of Chemical & Engineering Data
Volume62
Issue number1
Early online date30 Nov 2016
DOIs
Publication statusPublished - 12 Jan 2017

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anhydrides
equations of state
deviation
cells
temperature

Bibliographical note

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Chemical and Engineering Data, copyright ©2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.jced.6b00595

Cite this

Rebocho, Sílvia ; Nunes, Ana V. M. ; Najdanovic-Visak, Vesna ; Barreiros, Susana ; Paiva, Alexandre. / Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure. In: Journal of Chemical & Engineering Data. 2017 ; Vol. 62, No. 1. pp. 210-213.
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Rebocho, S, Nunes, AVM, Najdanovic-Visak, V, Barreiros, S & Paiva, A 2017, 'Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure', Journal of Chemical & Engineering Data, vol. 62, no. 1, pp. 210-213. https://doi.org/10.1021/acs.jced.6b00595

Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure. / Rebocho, Sílvia; Nunes, Ana V. M.; Najdanovic-Visak, Vesna; Barreiros, Susana; Paiva, Alexandre.

In: Journal of Chemical & Engineering Data, Vol. 62, No. 1, 12.01.2017, p. 210-213.

Research output: Contribution to journalArticle

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