TY - JOUR
T1 - Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure
AU - Rebocho, Sílvia
AU - Nunes, Ana V. M.
AU - Najdanovic-Visak, Vesna
AU - Barreiros, Susana
AU - Paiva, Alexandre
N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Chemical and Engineering Data, copyright ©2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.jced.6b00595
PY - 2017/1/12
Y1 - 2017/1/12
N2 - The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng–Robinson equation of state and the Mathias–Klotz–Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.
AB - The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng–Robinson equation of state and the Mathias–Klotz–Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.
UR - https://pubs.acs.org/doi/10.1021/acs.jced.6b00595
U2 - 10.1021/acs.jced.6b00595
DO - 10.1021/acs.jced.6b00595
M3 - Article
VL - 62
SP - 210
EP - 213
JO - Journal of Chemical & Engineering Data
JF - Journal of Chemical & Engineering Data
SN - 0021-9568
IS - 1
ER -