Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure

Sílvia Rebocho; Ana V. M. Nunes; Vesna Najdanovic-Visak; Susana Barreiros; Alexandre Paiva

doi:10.1021/acs.jced.6b00595

Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure

Sílvia Rebocho, Ana V. M. Nunes, Vesna Najdanovic-Visak, Susana Barreiros, Alexandre Paiva

Research output: Contribution to journal › Article

Abstract

The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng–Robinson equation of state and the Mathias–Klotz–Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.

Original language	English
Pages (from-to)	210-213
Journal	Journal of Chemical & Engineering Data
Volume	62
Issue number	1
Early online date	30 Nov 2016
DOIs	https://doi.org/10.1021/acs.jced.6b00595
Publication status	Published - 12 Jan 2017

Bibliographical note

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Chemical and Engineering Data, copyright ©2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.jced.6b00595

Access to Document

10.1021/acs.jced.6b00595

Experimental Determination
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Chemical and Engineering Data, copyright ©2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.jced.6b00595
Accepted author manuscript, 607 KB

Fingerprint Dive into the research topics of 'Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure'. Together they form a unique fingerprint.

Cite this

Rebocho, S., Nunes, A. V. M., Najdanovic-Visak, V., Barreiros, S., & Paiva, A. (2017). Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure. Journal of Chemical & Engineering Data, 62(1), 210-213. https://doi.org/10.1021/acs.jced.6b00595

@article{0c37977a98f7453bbc7453f2b90a278c,

title = "Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure",

abstract = "The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng–Robinson equation of state and the Mathias–Klotz–Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.",

author = "S{\'i}lvia Rebocho and Nunes, {Ana V. M.} and Vesna Najdanovic-Visak and Susana Barreiros and Alexandre Paiva",

note = "This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Chemical and Engineering Data, copyright {\textcopyright}2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.jced.6b00595",

year = "2017",

month = jan,

day = "12",

doi = "10.1021/acs.jced.6b00595",

language = "English",

volume = "62",

pages = "210--213",

journal = "Journal of Chemical & Engineering Data",

issn = "0021-9568",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure

AU - Rebocho, Sílvia

AU - Nunes, Ana V. M.

AU - Najdanovic-Visak, Vesna

AU - Barreiros, Susana

AU - Paiva, Alexandre

N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Chemical and Engineering Data, copyright ©2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.jced.6b00595

PY - 2017/1/12

Y1 - 2017/1/12

N2 - The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng–Robinson equation of state and the Mathias–Klotz–Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.

AB - The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng–Robinson equation of state and the Mathias–Klotz–Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.

UR - https://pubs.acs.org/doi/10.1021/acs.jced.6b00595

U2 - 10.1021/acs.jced.6b00595

DO - 10.1021/acs.jced.6b00595

M3 - Article

VL - 62

SP - 210

EP - 213

JO - Journal of Chemical & Engineering Data

JF - Journal of Chemical & Engineering Data

SN - 0021-9568

IS - 1

ER -