Facile route to conformal hydrotalcite coatings over complex architectures: a hierarchically ordered nanoporous base catalyst for FAME production

Julia J. Creasey; Christopher M.A. Parlett; Jinesh C. Manayil; Mark A. Issacs; Karen Wilson; Adam Lee

doi:10.1039/C4GC01689K

Facile route to conformal hydrotalcite coatings over complex architectures: a hierarchically ordered nanoporous base catalyst for FAME production

Julia J. Creasey
, Christopher M.A. Parlett
, Jinesh C. Manayil
, Mark A. Issacs
, Karen Wilson
, Adam Lee^*

^*Corresponding author for this work

Cardiff University
University of Warwick
European Synchrotron Radiation Facility

Research output: Contribution to journal › Article › peer-review

33 Citations (SciVal)

173 Downloads (Pure)

Abstract

An alkali- and nitrate-free hydrotalcite coating has been grafted onto the surface of a hierarchically ordered macroporous-mesoporous SBA-15 template via stepwise growth of conformal alumina adlayers and their subsequent reaction with magnesium methoxide. The resulting low dimensional hydrotalcite crystallites exhibit excellent per site activity for the base catalysed transesterification of glyceryl triolein with methanol for FAME production.

Original language	English
Pages (from-to)	2398-2405
Number of pages	8
Journal	Green Chemistry
Volume	17
Issue number	4
Early online date	27 Jan 2015
DOIs	https://doi.org/10.1039/C4GC01689K
Publication status	Published - Feb 2015

Bibliographical note

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. This journal is © The Royal Society of Chemistry 2015.

Funding: EPSRC (EP/G007594/4); Leadership Fellowship and studentship; Royal Society Industry Fellowship.

Supplementary data via publisher's website.

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10.1039/C4GC01689K

Hierarchically ordered nanoporous base catalyst for FAME production
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. This journal is © The Royal Society of Chemistry 2015.
Final published version, 2.44 MBLicence: CC BY 3.0

http://pubs.rsc.org/en/Content/ArticleLanding/2015/GC/c4gc01689k#!divAbstract

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title = "Facile route to conformal hydrotalcite coatings over complex architectures: a hierarchically ordered nanoporous base catalyst for FAME production",

abstract = "An alkali- and nitrate-free hydrotalcite coating has been grafted onto the surface of a hierarchically ordered macroporous-mesoporous SBA-15 template via stepwise growth of conformal alumina adlayers and their subsequent reaction with magnesium methoxide. The resulting low dimensional hydrotalcite crystallites exhibit excellent per site activity for the base catalysed transesterification of glyceryl triolein with methanol for FAME production.",

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AU - Issacs, Mark A.

AU - Wilson, Karen

AU - Lee, Adam

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AB - An alkali- and nitrate-free hydrotalcite coating has been grafted onto the surface of a hierarchically ordered macroporous-mesoporous SBA-15 template via stepwise growth of conformal alumina adlayers and their subsequent reaction with magnesium methoxide. The resulting low dimensional hydrotalcite crystallites exhibit excellent per site activity for the base catalysed transesterification of glyceryl triolein with methanol for FAME production.

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Facile route to conformal hydrotalcite coatings over complex architectures: a hierarchically ordered nanoporous base catalyst for FAME production

Abstract

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