Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane

James A. Hunns; Marta Arroyo; Adam F. Lee; José M. Escola; David Serrano; Karen Wilson

doi:10.1039/c5cy02072g

Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane

James A. Hunns
, Marta Arroyo
, Adam F. Lee
, José M. Escola
, David Serrano^*
, Karen Wilson

^*Corresponding author for this work

Universidad Rey Juan Carlos
Instituto IMDEA Energía

Research output: Contribution to journal › Article › peer-review

67 Citations (SciVal)

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Abstract

Mesopore incorporation into ZSM-5 enhances the dispersion of Pd nanoparticles throughout the hierarchical framework, significantly accelerating m-cresol conversion relative to a conventional microporous ZSM-5, and dramatically increasing selectivity towards the desired methylcyclohexane deoxygenated product. Increasing the acid site density further promotes m-cresol conversion and methylcyclohexane selectivity through efficient dehydration of the intermediate methylcyclohexanol.

Original language	English
Pages (from-to)	2560-2564
Number of pages	5
Journal	Catalysis Science and Technology
Volume	6
Issue number	8
Early online date	29 Dec 2015
DOIs	https://doi.org/10.1039/c5cy02072g
Publication status	Published - 21 Apr 2016

Bibliographical note

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Funding: EPSRC (EP/K036548/1 and EP/K014706/1), EU FP7 (FP7/2007-2013) grant agreement 604307

Electronic supplementary information: Full synthetic, characterisation and reaction details. See DOI:10.1039/c5cy02072g

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Selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane
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title = "Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane",

abstract = "Mesopore incorporation into ZSM-5 enhances the dispersion of Pd nanoparticles throughout the hierarchical framework, significantly accelerating m-cresol conversion relative to a conventional microporous ZSM-5, and dramatically increasing selectivity towards the desired methylcyclohexane deoxygenated product. Increasing the acid site density further promotes m-cresol conversion and methylcyclohexane selectivity through efficient dehydration of the intermediate methylcyclohexanol.",

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AU - Arroyo, Marta

AU - Lee, Adam F.

AU - Escola, José M.

AU - Serrano, David

AU - Wilson, Karen

N1 - This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Funding: EPSRC (EP/K036548/1 and EP/K014706/1), EU FP7 (FP7/2007-2013) grant agreement 604307 Electronic supplementary information: Full synthetic, characterisation and reaction details. See DOI:10.1039/c5cy02072g

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N2 - Mesopore incorporation into ZSM-5 enhances the dispersion of Pd nanoparticles throughout the hierarchical framework, significantly accelerating m-cresol conversion relative to a conventional microporous ZSM-5, and dramatically increasing selectivity towards the desired methylcyclohexane deoxygenated product. Increasing the acid site density further promotes m-cresol conversion and methylcyclohexane selectivity through efficient dehydration of the intermediate methylcyclohexanol.

AB - Mesopore incorporation into ZSM-5 enhances the dispersion of Pd nanoparticles throughout the hierarchical framework, significantly accelerating m-cresol conversion relative to a conventional microporous ZSM-5, and dramatically increasing selectivity towards the desired methylcyclohexane deoxygenated product. Increasing the acid site density further promotes m-cresol conversion and methylcyclohexane selectivity through efficient dehydration of the intermediate methylcyclohexanol.

UR - https://www.scopus.com/pages/publications/84966400931

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ER -

Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane

Abstract

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