High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols

Simon F.J. Hackett; Rik M. Brydson; Mhairi H. Gass; Ian Harvey; Andrew D. Newman; Karen Wilson; Adam F. Lee

doi:10.1002/anie.200702534

High-activity, single-site mesoporous Pd/Al₂O₃ catalysts for selective aerobic oxidation of allylic alcohols

Simon F.J. Hackett, Rik M. Brydson, Mhairi H. Gass, Ian Harvey, Andrew D. Newman, Karen Wilson, Adam F. Lee

Research output: Contribution to journal › Article › peer-review

Abstract

Pd does it alone: Tailored heterogeneous catalysts offer exciting, alternative, clean technologies for regioselective molecular transformations. A mesoporous alumina support stabilizes atomically dispersed Pd^II surface sites (see picture, C light gray, O red, Pd dark gray, Al purple, H white), thereby dramatically enhancing catalytic performance in the aerobic selective oxidation of alcohols.

Original language	English
Pages (from-to)	8593-8596
Number of pages	4
Journal	Angewandte Chemie
Volume	46
Issue number	45
Early online date	5 Oct 2007
DOIs	https://doi.org/10.1002/anie.200702534
Publication status	Published - 19 Nov 2007

Bibliographical note

Funding: EPSRC (EP/E046754/1, EP/P500575/1)

Keywords

heterogeneous catalysis
mesoporous materials
oxidation
palladium
X-ray absorption spectroscopy

Access to Document

10.1002/anie.200702534

Cite this

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title = "High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols",

abstract = "Pd does it alone: Tailored heterogeneous catalysts offer exciting, alternative, clean technologies for regioselective molecular transformations. A mesoporous alumina support stabilizes atomically dispersed PdII surface sites (see picture, C light gray, O red, Pd dark gray, Al purple, H white), thereby dramatically enhancing catalytic performance in the aerobic selective oxidation of alcohols.",

keywords = "heterogeneous catalysis, mesoporous materials, oxidation, palladium, X-ray absorption spectroscopy",

author = "Simon F.J. Hackett and Brydson, {Rik M.} and Mhairi H. Gass and Ian Harvey and Newman, {Andrew D.} and Karen Wilson and Lee, {Adam F.}",

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T1 - High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols

AU - Hackett, Simon F.J.

AU - Brydson, Rik M.

AU - Gass, Mhairi H.

AU - Harvey, Ian

AU - Newman, Andrew D.

AU - Wilson, Karen

AU - Lee, Adam F.

N1 - Funding: EPSRC (EP/E046754/1, EP/P500575/1)

PY - 2007/11/19

Y1 - 2007/11/19

N2 - Pd does it alone: Tailored heterogeneous catalysts offer exciting, alternative, clean technologies for regioselective molecular transformations. A mesoporous alumina support stabilizes atomically dispersed PdII surface sites (see picture, C light gray, O red, Pd dark gray, Al purple, H white), thereby dramatically enhancing catalytic performance in the aerobic selective oxidation of alcohols.

AB - Pd does it alone: Tailored heterogeneous catalysts offer exciting, alternative, clean technologies for regioselective molecular transformations. A mesoporous alumina support stabilizes atomically dispersed PdII surface sites (see picture, C light gray, O red, Pd dark gray, Al purple, H white), thereby dramatically enhancing catalytic performance in the aerobic selective oxidation of alcohols.

KW - heterogeneous catalysis

KW - mesoporous materials

KW - oxidation

KW - palladium

KW - X-ray absorption spectroscopy

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