High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols

Simon F.J. Hackett, Rik M. Brydson, Mhairi H. Gass, Ian Harvey, Andrew D. Newman, Karen Wilson, Adam F. Lee

Research output: Contribution to journalArticle

Abstract

Pd does it alone: Tailored heterogeneous catalysts offer exciting, alternative, clean technologies for regioselective molecular transformations. A mesoporous alumina support stabilizes atomically dispersed PdII surface sites (see picture, C light gray, O red, Pd dark gray, Al purple, H white), thereby dramatically enhancing catalytic performance in the aerobic selective oxidation of alcohols.
Original languageEnglish
Pages (from-to)8593-8596
Number of pages4
JournalAngewandte Chemie
Volume46
Issue number45
Early online date5 Oct 2007
DOIs
Publication statusPublished - 19 Nov 2007

Fingerprint

Environmental technology
Aluminum Oxide
Alcohols
Alumina
Oxidation
Catalysts
allyl alcohol

Bibliographical note

Funding: EPSRC (EP/E046754/1, EP/P500575/1)

Keywords

  • heterogeneous catalysis
  • mesoporous materials
  • oxidation
  • palladium
  • X-ray absorption spectroscopy

Cite this

Hackett, SF. J., Brydson, R. M., Gass, MH., Harvey, I., Newman, A. D., Wilson, K., & Lee, A. F. (2007). High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols. Angewandte Chemie, 46(45), 8593-8596. https://doi.org/10.1002/anie.200702534
Hackett, Simon F.J. ; Brydson, Rik M. ; Gass, Mhairi H. ; Harvey, Ian ; Newman, Andrew D. ; Wilson, Karen ; Lee, Adam F. / High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols. In: Angewandte Chemie. 2007 ; Vol. 46, No. 45. pp. 8593-8596.
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Hackett, SFJ, Brydson, RM, Gass, MH, Harvey, I, Newman, AD, Wilson, K & Lee, AF 2007, 'High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols', Angewandte Chemie, vol. 46, no. 45, pp. 8593-8596. https://doi.org/10.1002/anie.200702534

High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols. / Hackett, Simon F.J.; Brydson, Rik M.; Gass, Mhairi H.; Harvey, Ian; Newman, Andrew D.; Wilson, Karen; Lee, Adam F.

In: Angewandte Chemie, Vol. 46, No. 45, 19.11.2007, p. 8593-8596.

Research output: Contribution to journalArticle

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T1 - High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols

AU - Hackett, Simon F.J.

AU - Brydson, Rik M.

AU - Gass, Mhairi H.

AU - Harvey, Ian

AU - Newman, Andrew D.

AU - Wilson, Karen

AU - Lee, Adam F.

N1 - Funding: EPSRC (EP/E046754/1, EP/P500575/1)

PY - 2007/11/19

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AB - Pd does it alone: Tailored heterogeneous catalysts offer exciting, alternative, clean technologies for regioselective molecular transformations. A mesoporous alumina support stabilizes atomically dispersed PdII surface sites (see picture, C light gray, O red, Pd dark gray, Al purple, H white), thereby dramatically enhancing catalytic performance in the aerobic selective oxidation of alcohols.

KW - heterogeneous catalysis

KW - mesoporous materials

KW - oxidation

KW - palladium

KW - X-ray absorption spectroscopy

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