High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal

Rajesh Kumar Ulaganathan; Pradip Kumar Roy; Swapnil Milind Mhatre; Raghavan Chinnambedu Murugesan; Wei-Liang Chen; Man-Hong Lai; Ambika Subramanian; Chang-Yu Lin; Yu-Ming Chang; Stela Canulescu; Alex Rozhin; Chi-Te Liang; Raman Sankar

doi:10.1002/adfm.202214078

High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal

Rajesh Kumar Ulaganathan, Pradip Kumar Roy, Swapnil Milind Mhatre, Raghavan Chinnambedu Murugesan, Wei-Liang Chen, Man-Hong Lai, Ambika Subramanian, Chang-Yu Lin, Yu-Ming Chang, Stela Canulescu, Alex Rozhin, Chi-Te Liang, Raman Sankar

Research output: Contribution to journal › Article › peer-review

Abstract

3D organic-inorganic metal halide perovskites are excellent materials for optoelectronic applications due to their exceptional properties, solution processability, and cost-effectiveness. However, the lack of environmental stability highly restricts them from practical applications. Herein, a stable centimeter-long 2D hybrid perovskite (N-MPDA)[PbBr4] single crystal using divalent N1-methylpropane-1,3-diammonium (N-MPDA) cation as an organic spacer, is reported. The as-grown single crystal exhibits stable optoelectronic performance, low threshold random lasing, and multi-photon luminescence/multi-harmonic generation. A photoconductive device fabricated using (N-MPDA)[PbBr4] single crystal exhibits an excellent photoresponsivity (≈124 AW?1 at 405 nm) that is ≈4 orders of magnitudes higher than that of monovalent organic spacer-assisted 2D perovskites, such as (BA)2PbBr4 and (PEA)2PbBr4, and large specific detectivity (≈1012 Jones). As an optical gain media, the (N-MPDA)[PbBr4] single crystal exhibits a low threshold random lasing (≈6.5 µJ cm?2) with angular dependent narrow linewidth (≈0.1 nm) and high-quality factor (Q ≈ 2673). Based on these results, the outstanding optoelectronic merits of (N-MPDA)[PbBr4] single crystal will offer a high-performance device and act as a dynamic material to construct stable future electronics and optoelectronic-based applications.

Original language	English
Article number	2214078
Number of pages	10
Journal	Advanced Functional Materials
Volume	33
Issue number	17
Early online date	7 Feb 2023
DOIs	https://doi.org/10.1002/adfm.202214078
Publication status	E-pub ahead of print - 7 Feb 2023

Bibliographical note

This is the peer reviewed version of the following article: Ulaganathan, R. K et al. High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal. Adv. Funct. Mater. 2023, 2214078., which has been published in final form at https://doi.org/10.1002/adfm.202214078. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.

Keywords

long-chain spacers
optoelectronics
random lasing
responsivity
second-harmonic generation

Access to Document

10.1002/adfm.202214078

Ulaganathanetal_2023_AAM
This is the peer reviewed version of the following article: Ulaganathan, R. K et al. High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal. Adv. Funct. Mater. 2023, 2214078., which has been published in final form at https://doi.org/10.1002/adfm.202214078. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.
Accepted author manuscript, 3.84 MBLicence: Other

Cite this

Ulaganathan, R. K., Roy, P. K., Mhatre, S. M., Murugesan, R. C., Chen, W.-L., Lai, M.-H., Subramanian, A., Lin, C.-Y., Chang, Y.-M., Canulescu, S., Rozhin, A., Liang, C.-T., & Sankar, R. (2023). High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal. Advanced Functional Materials, 33(17), Article 2214078. Advance online publication. https://doi.org/10.1002/adfm.202214078

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title = "High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal",

abstract = "3D organic-inorganic metal halide perovskites are excellent materials for optoelectronic applications due to their exceptional properties, solution processability, and cost-effectiveness. However, the lack of environmental stability highly restricts them from practical applications. Herein, a stable centimeter-long 2D hybrid perovskite (N-MPDA)[PbBr4] single crystal using divalent N1-methylpropane-1,3-diammonium (N-MPDA) cation as an organic spacer, is reported. The as-grown single crystal exhibits stable optoelectronic performance, low threshold random lasing, and multi-photon luminescence/multi-harmonic generation. A photoconductive device fabricated using (N-MPDA)[PbBr4] single crystal exhibits an excellent photoresponsivity (≈124 AW?1 at 405 nm) that is ≈4 orders of magnitudes higher than that of monovalent organic spacer-assisted 2D perovskites, such as (BA)2PbBr4 and (PEA)2PbBr4, and large specific detectivity (≈1012 Jones). As an optical gain media, the (N-MPDA)[PbBr4] single crystal exhibits a low threshold random lasing (≈6.5 µJ cm?2) with angular dependent narrow linewidth (≈0.1 nm) and high-quality factor (Q ≈ 2673). Based on these results, the outstanding optoelectronic merits of (N-MPDA)[PbBr4] single crystal will offer a high-performance device and act as a dynamic material to construct stable future electronics and optoelectronic-based applications.",

keywords = "long-chain spacers, optoelectronics, random lasing, responsivity, second-harmonic generation",

author = "Ulaganathan, {Rajesh Kumar} and Roy, {Pradip Kumar} and Mhatre, {Swapnil Milind} and Murugesan, {Raghavan Chinnambedu} and Wei-Liang Chen and Man-Hong Lai and Ambika Subramanian and Chang-Yu Lin and Yu-Ming Chang and Stela Canulescu and Alex Rozhin and Chi-Te Liang and Raman Sankar",

note = "This is the peer reviewed version of the following article: Ulaganathan, R. K et al. High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal. Adv. Funct. Mater. 2023, 2214078., which has been published in final form at https://doi.org/10.1002/adfm.202214078. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley{\textquoteright}s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.",

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language = "English",

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Ulaganathan, RK, Roy, PK, Mhatre, SM, Murugesan, RC, Chen, W-L, Lai, M-H, Subramanian, A, Lin, C-Y, Chang, Y-M, Canulescu, S, Rozhin, A, Liang, C-T & Sankar, R 2023, 'High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal', Advanced Functional Materials, vol. 33, no. 17, 2214078. https://doi.org/10.1002/adfm.202214078

High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal. / Ulaganathan, Rajesh Kumar; Roy, Pradip Kumar; Mhatre, Swapnil Milind et al.
In: Advanced Functional Materials, Vol. 33, No. 17, 2214078, 07.02.2023.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal

AU - Ulaganathan, Rajesh Kumar

AU - Roy, Pradip Kumar

AU - Mhatre, Swapnil Milind

AU - Murugesan, Raghavan Chinnambedu

AU - Chen, Wei-Liang

AU - Lai, Man-Hong

AU - Subramanian, Ambika

AU - Lin, Chang-Yu

AU - Chang, Yu-Ming

AU - Canulescu, Stela

AU - Rozhin, Alex

AU - Liang, Chi-Te

AU - Sankar, Raman

N1 - This is the peer reviewed version of the following article: Ulaganathan, R. K et al. High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal. Adv. Funct. Mater. 2023, 2214078., which has been published in final form at https://doi.org/10.1002/adfm.202214078. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.

PY - 2023/2/7

Y1 - 2023/2/7

N2 - 3D organic-inorganic metal halide perovskites are excellent materials for optoelectronic applications due to their exceptional properties, solution processability, and cost-effectiveness. However, the lack of environmental stability highly restricts them from practical applications. Herein, a stable centimeter-long 2D hybrid perovskite (N-MPDA)[PbBr4] single crystal using divalent N1-methylpropane-1,3-diammonium (N-MPDA) cation as an organic spacer, is reported. The as-grown single crystal exhibits stable optoelectronic performance, low threshold random lasing, and multi-photon luminescence/multi-harmonic generation. A photoconductive device fabricated using (N-MPDA)[PbBr4] single crystal exhibits an excellent photoresponsivity (≈124 AW?1 at 405 nm) that is ≈4 orders of magnitudes higher than that of monovalent organic spacer-assisted 2D perovskites, such as (BA)2PbBr4 and (PEA)2PbBr4, and large specific detectivity (≈1012 Jones). As an optical gain media, the (N-MPDA)[PbBr4] single crystal exhibits a low threshold random lasing (≈6.5 µJ cm?2) with angular dependent narrow linewidth (≈0.1 nm) and high-quality factor (Q ≈ 2673). Based on these results, the outstanding optoelectronic merits of (N-MPDA)[PbBr4] single crystal will offer a high-performance device and act as a dynamic material to construct stable future electronics and optoelectronic-based applications.

AB - 3D organic-inorganic metal halide perovskites are excellent materials for optoelectronic applications due to their exceptional properties, solution processability, and cost-effectiveness. However, the lack of environmental stability highly restricts them from practical applications. Herein, a stable centimeter-long 2D hybrid perovskite (N-MPDA)[PbBr4] single crystal using divalent N1-methylpropane-1,3-diammonium (N-MPDA) cation as an organic spacer, is reported. The as-grown single crystal exhibits stable optoelectronic performance, low threshold random lasing, and multi-photon luminescence/multi-harmonic generation. A photoconductive device fabricated using (N-MPDA)[PbBr4] single crystal exhibits an excellent photoresponsivity (≈124 AW?1 at 405 nm) that is ≈4 orders of magnitudes higher than that of monovalent organic spacer-assisted 2D perovskites, such as (BA)2PbBr4 and (PEA)2PbBr4, and large specific detectivity (≈1012 Jones). As an optical gain media, the (N-MPDA)[PbBr4] single crystal exhibits a low threshold random lasing (≈6.5 µJ cm?2) with angular dependent narrow linewidth (≈0.1 nm) and high-quality factor (Q ≈ 2673). Based on these results, the outstanding optoelectronic merits of (N-MPDA)[PbBr4] single crystal will offer a high-performance device and act as a dynamic material to construct stable future electronics and optoelectronic-based applications.

KW - long-chain spacers

KW - optoelectronics

KW - random lasing

KW - responsivity

KW - second-harmonic generation

UR - https://onlinelibrary.wiley.com/doi/10.1002/adfm.202214078

U2 - 10.1002/adfm.202214078

DO - 10.1002/adfm.202214078

M3 - Article

SN - 1616-301X

VL - 33

JO - Advanced Functional Materials

JF - Advanced Functional Materials

IS - 17

M1 - 2214078

ER -

High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal

Abstract

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Keywords

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