Highly Water-Stable Zirconium Metal-Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination

Xinlei Liu, Nilay Keser Demir, Zhentao Wu, Kang Li*

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

In this study, continuous zirconium(IV)-based metal-organic framework (Zr-MOF) membranes were prepared. The pure-phase Zr-MOF (i.e., UiO-66) polycrystalline membranes were fabricated on alumina hollow fibers using an in situ solvothermal synthesis method. Single-gas permeation and ion rejection tests were carried out to confirm membrane integrity and functionality. The membrane exhibited excellent multivalent ion rejection (e.g., 86.3% for Ca2+, 98.0% for Mg2+, and 99.3% for Al3+) on the basis of size exclusion with moderate permeance (0.14 L m-2 h-1 bar-1) and good permeability (0.28 L m-2 h-1 bar-1 μm). Benefiting from the exceptional chemical stability of the UiO-66 material, no degradation of membrane performance was observed for various tests up to 170 h toward a wide range of saline solutions. The high separation performance combined with its outstanding water stability suggests the developed UiO-66 membrane as a promising candidate for water desalination.

Original languageEnglish
Pages (from-to)6999-7002
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number22
DOIs
Publication statusPublished - 10 Jun 2015

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Aluminum Oxide
Desalination
Zirconium
Alumina
Metals
Membranes
Water
Fibers
Ions
Chemical stability
Sodium Chloride
Permeation
Permeability
Gases
Degradation

Bibliographical note

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, © 2015 American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/jacs.5b02276.

Cite this

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title = "Highly Water-Stable Zirconium Metal-Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination",
abstract = "In this study, continuous zirconium(IV)-based metal-organic framework (Zr-MOF) membranes were prepared. The pure-phase Zr-MOF (i.e., UiO-66) polycrystalline membranes were fabricated on alumina hollow fibers using an in situ solvothermal synthesis method. Single-gas permeation and ion rejection tests were carried out to confirm membrane integrity and functionality. The membrane exhibited excellent multivalent ion rejection (e.g., 86.3{\%} for Ca2+, 98.0{\%} for Mg2+, and 99.3{\%} for Al3+) on the basis of size exclusion with moderate permeance (0.14 L m-2 h-1 bar-1) and good permeability (0.28 L m-2 h-1 bar-1 μm). Benefiting from the exceptional chemical stability of the UiO-66 material, no degradation of membrane performance was observed for various tests up to 170 h toward a wide range of saline solutions. The high separation performance combined with its outstanding water stability suggests the developed UiO-66 membrane as a promising candidate for water desalination.",
author = "Xinlei Liu and Demir, {Nilay Keser} and Zhentao Wu and Kang Li",
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Highly Water-Stable Zirconium Metal-Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination. / Liu, Xinlei; Demir, Nilay Keser; Wu, Zhentao; Li, Kang.

In: Journal of the American Chemical Society, Vol. 137, No. 22, 10.06.2015, p. 6999-7002.

Research output: Contribution to journalArticle

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