In situ studies of phase separation and crystallization directed by Marangoni instabilities during spin-coating

Daniel T.W. Toolan, Nikki Pullan, Michael J. Harvey, Paul D. Topham, Jonathan R. Howse*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Results of a pioneering study are presented in which for the first time, crystallization, phase separation and Marangoni instabilities occurring during the spin-coating of polymer blends are directly visualized, in real-space and real-time. The results provide exciting new insights into the process of self-assembly, taking place during spin-coating, paving the way for the rational design of processing conditions, to allow desired morphologies to be obtained.

Original languageEnglish
Pages (from-to)7033-7037
Number of pages5
JournalAdvanced Materials
Volume25
Issue number48
Early online date7 Oct 2013
DOIs
Publication statusPublished - 23 Dec 2013

Bibliographical note

Funding: EPSRC through a CASE studentship; Robinson Brothers Ltd.

Supporting Information is available from the Wiley Online Library or
from the author.

Keywords

  • microstructures
  • polymeric materials
  • self-assembly
  • spin-coating
  • thin films

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