Results of a pioneering study are presented in which for the first time, crystallization, phase separation and Marangoni instabilities occurring during the spin-coating of polymer blends are directly visualized, in real-space and real-time. The results provide exciting new insights into the process of self-assembly, taking place during spin-coating, paving the way for the rational design of processing conditions, to allow desired morphologies to be obtained.
Bibliographical noteFunding: EPSRC through a CASE studentship; Robinson Brothers Ltd.
Supporting Information is available from the Wiley Online Library or
from the author.
- polymeric materials
- thin films