Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites

Mohd Shaiful Zaidi Mat Desa, Azman Hassan, Agus Arsad, Reza Arjmandi, Nor Nisa Balqis Mohammad

Research output: Contribution to journalArticle

Abstract

The effects of natural rubber (NR) on the mechanical, thermal, and morphological properties of multiwalled carbon nanotube (CNT) reinforced poly(lactic acid) (PLA) nanocomposites prepared by melt blending were investigated. A PLA/NR blend and PLA/CNT nanocomposites were also produced for comparison. The tensile strength and Young's modulus of PLA/CNT nanocomposites improved significantly, whereas the impact strength decreased compared to neat PLA. The incorporation of NR into PLA/CNT significantly improved the impact strength and elongation at break of the nanocomposites, which showed approximately 200% and 850% increases at 20 wt % NR, respectively. However, the tensile strength and Young's modulus of PLA/NR/CNT nanocomposites decreased compared to PLA/CNT nanocomposites. The morphology analysis showed the homogeneous dispersion of NR particles in PLA/NR/CNT nanocomposites, while CNTs preferentially reside in the NR phase rather than the PLA matrix. In addition, the incorporation of NR into PLA/CNT lowered the thermal stability and glass‐transition temperature of the nanocomposites.
Original languageEnglish
JournalJournal of Applied Polymer Science
Volume133
Issue number48
Early online date30 Aug 2016
DOIs
Publication statusPublished - 20 Dec 2016

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Multiwalled carbon nanotubes (MWCN)
Rubber
Lactic acid
Nanocomposites
Carbon Nanotubes
Carbon nanotubes
Impact strength
Hot Temperature
poly(lactic acid)
Tensile strength
Elastic moduli
Elongation
Thermodynamic stability

Cite this

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title = "Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites",
abstract = "The effects of natural rubber (NR) on the mechanical, thermal, and morphological properties of multiwalled carbon nanotube (CNT) reinforced poly(lactic acid) (PLA) nanocomposites prepared by melt blending were investigated. A PLA/NR blend and PLA/CNT nanocomposites were also produced for comparison. The tensile strength and Young's modulus of PLA/CNT nanocomposites improved significantly, whereas the impact strength decreased compared to neat PLA. The incorporation of NR into PLA/CNT significantly improved the impact strength and elongation at break of the nanocomposites, which showed approximately 200{\%} and 850{\%} increases at 20 wt {\%} NR, respectively. However, the tensile strength and Young's modulus of PLA/NR/CNT nanocomposites decreased compared to PLA/CNT nanocomposites. The morphology analysis showed the homogeneous dispersion of NR particles in PLA/NR/CNT nanocomposites, while CNTs preferentially reside in the NR phase rather than the PLA matrix. In addition, the incorporation of NR into PLA/CNT lowered the thermal stability and glass‐transition temperature of the nanocomposites.",
author = "{Mat Desa}, {Mohd Shaiful Zaidi} and Azman Hassan and Agus Arsad and Reza Arjmandi and Mohammad, {Nor Nisa Balqis}",
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Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites. / Mat Desa, Mohd Shaiful Zaidi; Hassan, Azman; Arsad, Agus; Arjmandi, Reza; Mohammad, Nor Nisa Balqis.

In: Journal of Applied Polymer Science, Vol. 133, No. 48, 20.12.2016.

Research output: Contribution to journalArticle

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AU - Mohammad, Nor Nisa Balqis

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AB - The effects of natural rubber (NR) on the mechanical, thermal, and morphological properties of multiwalled carbon nanotube (CNT) reinforced poly(lactic acid) (PLA) nanocomposites prepared by melt blending were investigated. A PLA/NR blend and PLA/CNT nanocomposites were also produced for comparison. The tensile strength and Young's modulus of PLA/CNT nanocomposites improved significantly, whereas the impact strength decreased compared to neat PLA. The incorporation of NR into PLA/CNT significantly improved the impact strength and elongation at break of the nanocomposites, which showed approximately 200% and 850% increases at 20 wt % NR, respectively. However, the tensile strength and Young's modulus of PLA/NR/CNT nanocomposites decreased compared to PLA/CNT nanocomposites. The morphology analysis showed the homogeneous dispersion of NR particles in PLA/NR/CNT nanocomposites, while CNTs preferentially reside in the NR phase rather than the PLA matrix. In addition, the incorporation of NR into PLA/CNT lowered the thermal stability and glass‐transition temperature of the nanocomposites.

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