TY - CHAP
T1 - Iron(III) spin crossover compounds
AU - van Koningsbruggen, Petra J.
AU - Maeda, Yonezo
AU - Oshio, Hiroki
PY - 2004
Y1 - 2004
N2 - In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio-β-diketonates and X-semicarbazones (X=S, Se). In addition, attention is directed to Fe(III) spin crossover systems of multidentate Schiff base-type ligands. Examples of spin inter-conversion in Fe(III) compounds induced by light irradiation are given.
AB - In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio-β-diketonates and X-semicarbazones (X=S, Se). In addition, attention is directed to Fe(III) spin crossover systems of multidentate Schiff base-type ligands. Examples of spin inter-conversion in Fe(III) compounds induced by light irradiation are given.
UR - http://link.springer.com/chapter/10.1007/b95409
U2 - 10.1007/b95409
DO - 10.1007/b95409
M3 - Chapter (peer-reviewed)
SN - 978-3-540-40394-4
VL - 233
T3 - Topics in current chemistry
SP - 259
EP - 324
BT - Spin crossover in transition metal compounds I
A2 - Gütlich, P.
A2 - Goodwin, H.A.
PB - Springer
CY - Berlin (DE)
ER -