Kinetic Compensation Effect in Logistic Distributed Activation Energy Model for Lignocellulosic Biomass Pyrolysis

Di Xu, Meiyun Chai, Zhujun Dong, Md.Maksudur Rahman, Xi Yu, Junmeng Cai

Research output: Contribution to journalArticle

Abstract

The kinetic compensation effect in the logistic distributed activation energy model (DAEM) for lignocellulosic biomass pyrolysis was investigated. The sum of square error (SSE) surface tool was used to analyze two theoretically simulated logistic DAEM processes for cellulose and xylan pyrolysis. The logistic DAEM coupled with the pattern search method for parameter estimation was used to analyze the experimental data of cellulose pyrolysis. The results showed that many parameter sets of the logistic DAEM could fit the data at different heating rates very well for both simulated and experimental processes, and a perfect linear relationship between the logarithm of the frequency factor and the mean value of the activation energy distribution was found. The parameters of the logistic DAEM can be estimated by coupling the optimization method and isoconversional kinetic methods. The results would be helpful for chemical kinetic analysis using DAEM.
Original languageEnglish
Pages (from-to)139-145
JournalBioresource Technology
Volume265
Early online date4 Jun 2018
DOIs
Publication statusPublished - 1 Oct 2018

Fingerprint

activation energy
pyrolysis
Logistics
logistics
Biomass
Pyrolysis
Activation energy
kinetics
Kinetics
biomass
Cellulose
cellulose
Xylans
Compensation and Redress
effect
Heating rate
Reaction kinetics
Parameter estimation
heating
method

Bibliographical note

© 2018, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/

Cite this

Xu, Di ; Chai, Meiyun ; Dong, Zhujun ; Rahman, Md.Maksudur ; Yu, Xi ; Cai, Junmeng. / Kinetic Compensation Effect in Logistic Distributed Activation Energy Model for Lignocellulosic Biomass Pyrolysis. In: Bioresource Technology. 2018 ; Vol. 265. pp. 139-145.
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abstract = "The kinetic compensation effect in the logistic distributed activation energy model (DAEM) for lignocellulosic biomass pyrolysis was investigated. The sum of square error (SSE) surface tool was used to analyze two theoretically simulated logistic DAEM processes for cellulose and xylan pyrolysis. The logistic DAEM coupled with the pattern search method for parameter estimation was used to analyze the experimental data of cellulose pyrolysis. The results showed that many parameter sets of the logistic DAEM could fit the data at different heating rates very well for both simulated and experimental processes, and a perfect linear relationship between the logarithm of the frequency factor and the mean value of the activation energy distribution was found. The parameters of the logistic DAEM can be estimated by coupling the optimization method and isoconversional kinetic methods. The results would be helpful for chemical kinetic analysis using DAEM.",
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Kinetic Compensation Effect in Logistic Distributed Activation Energy Model for Lignocellulosic Biomass Pyrolysis. / Xu, Di; Chai, Meiyun; Dong, Zhujun; Rahman, Md.Maksudur; Yu, Xi; Cai, Junmeng.

In: Bioresource Technology, Vol. 265, 01.10.2018, p. 139-145.

Research output: Contribution to journalArticle

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T1 - Kinetic Compensation Effect in Logistic Distributed Activation Energy Model for Lignocellulosic Biomass Pyrolysis

AU - Xu, Di

AU - Chai, Meiyun

AU - Dong, Zhujun

AU - Rahman, Md.Maksudur

AU - Yu, Xi

AU - Cai, Junmeng

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