Layered Double Hydroxides as Potential Sorbents for Water Remediation.

Paulmanickam Koilraj, Jinesh C. Manayil, Kannan Srinivasan

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Layered double hydroxides (LDHs) otherwise referred as hydrotalcite-like (HTlike) materials are potential sorbents that are explored widely in the field of waste water remediation of noxious anions. The structural features of LDHs makes them effective sorbents for these anions through different mechanism like surface adsorption, anionexchange, reconstruction and surface precipitation. This chapter presents a discussion about LDHs, their synthesis methodologies, physicochemical characterization and their potential in the removal of environmentally undesired oxoanions like phosphate, borate and chromate from aqueous solutions. The optimization of the various parameters like sorbate concentration, pH, temperature, time, extent of removal in the co-presence of competitive anions and reusability are discussed in respective sections. A comparison of the anionexchange capacity of LDHs with commercial anion exchangers is also discussed. Different mechanisms involved in the removal of phosphate, borate and chromate anions by LDHs are addressed.
Original languageEnglish
Title of host publicationApplication of Adsorbents for Water Pollution Control
EditorsAmit Bhatnagar
PublisherBentham
Pages153-237
ISBN (Electronic)978-1-60805-269-1
ISBN (Print)978-1-60805-538-8
DOIs
Publication statusPublished - Nov 2012

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Hydroxides
Sorbents
Remediation
Anions
Water
Chromates
Borates
hydrotalcite
Phosphates
Reusability
Wastewater
Adsorption

Cite this

Koilraj, P., C. Manayil, J., & Srinivasan, K. (2012). Layered Double Hydroxides as Potential Sorbents for Water Remediation. In A. Bhatnagar (Ed.), Application of Adsorbents for Water Pollution Control (pp. 153-237). Bentham. https://doi.org/10.2174/97816080526911120101
Koilraj, Paulmanickam ; C. Manayil, Jinesh ; Srinivasan, Kannan. / Layered Double Hydroxides as Potential Sorbents for Water Remediation. Application of Adsorbents for Water Pollution Control. editor / Amit Bhatnagar. Bentham, 2012. pp. 153-237
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Koilraj, P, C. Manayil, J & Srinivasan, K 2012, Layered Double Hydroxides as Potential Sorbents for Water Remediation. in A Bhatnagar (ed.), Application of Adsorbents for Water Pollution Control. Bentham, pp. 153-237. https://doi.org/10.2174/97816080526911120101

Layered Double Hydroxides as Potential Sorbents for Water Remediation. / Koilraj, Paulmanickam; C. Manayil, Jinesh; Srinivasan, Kannan.

Application of Adsorbents for Water Pollution Control. ed. / Amit Bhatnagar. Bentham, 2012. p. 153-237.

Research output: Chapter in Book/Report/Conference proceedingChapter

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N2 - Layered double hydroxides (LDHs) otherwise referred as hydrotalcite-like (HTlike) materials are potential sorbents that are explored widely in the field of waste water remediation of noxious anions. The structural features of LDHs makes them effective sorbents for these anions through different mechanism like surface adsorption, anionexchange, reconstruction and surface precipitation. This chapter presents a discussion about LDHs, their synthesis methodologies, physicochemical characterization and their potential in the removal of environmentally undesired oxoanions like phosphate, borate and chromate from aqueous solutions. The optimization of the various parameters like sorbate concentration, pH, temperature, time, extent of removal in the co-presence of competitive anions and reusability are discussed in respective sections. A comparison of the anionexchange capacity of LDHs with commercial anion exchangers is also discussed. Different mechanisms involved in the removal of phosphate, borate and chromate anions by LDHs are addressed.

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Koilraj P, C. Manayil J, Srinivasan K. Layered Double Hydroxides as Potential Sorbents for Water Remediation. In Bhatnagar A, editor, Application of Adsorbents for Water Pollution Control. Bentham. 2012. p. 153-237 https://doi.org/10.2174/97816080526911120101