Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix

A. Hernandez-Cid, M. Piekarska, R.W. Adams, M. Nilsson, R. Evans, G.A. Morris

Research output: Contribution to journalArticle

Abstract

Mixtures of species of similar sizes can be analysed with 1H NMR using diffusion-ordered spectroscopy (DOSY), by adding a co-solute with which different analytes interact to different extents (“matrix-assisted DOSY”). A matrix containing aqueous perfluorooctanoate micelles has the dual advantages of invisibility to 1H NMR, and interactions tuneable by adjusting the pH.
LanguageEnglish
Pages10757-10762
Number of pages6
JournalRSC advances
Volume7
Issue number18
Early online date8 Feb 2017
DOIs
Publication statusPublished - 2017

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perfluorooctanoic acid
Nuclear magnetic resonance spectroscopy
Nuclear magnetic resonance
Spectroscopy
Micelles

Bibliographical note

© The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Funding: EPSRC (EP/E05899X/1 and EP/H024336/1); Mexican Scientific and Technology Council (CONACyT); and Analytical Chemistry Trust Fund (summer studentship ACSS12/012).

Cite this

Hernandez-Cid, A., Piekarska, M., Adams, R. W., Nilsson, M., Evans, R., & Morris, G. A. (2017). Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix. RSC advances, 7(18), 10757-10762. https://doi.org/10.1039/C7RA00188F
Hernandez-Cid, A. ; Piekarska, M. ; Adams, R.W. ; Nilsson, M. ; Evans, R. ; Morris, G.A. / Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix. In: RSC advances. 2017 ; Vol. 7, No. 18. pp. 10757-10762.
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Hernandez-Cid, A, Piekarska, M, Adams, RW, Nilsson, M, Evans, R & Morris, GA 2017, 'Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix' RSC advances, vol. 7, no. 18, pp. 10757-10762. https://doi.org/10.1039/C7RA00188F

Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix. / Hernandez-Cid, A.; Piekarska, M.; Adams, R.W.; Nilsson, M.; Evans, R.; Morris, G.A.

In: RSC advances, Vol. 7, No. 18, 2017, p. 10757-10762.

Research output: Contribution to journalArticle

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