Mechanisms of antioxidant action: the role of nitroxyl radicals in the stabilization of PVC

Jacob B. Adeniyi, Sahar Al-Malaika, Gerald Scott

Research output: Contribution to journalArticle

Abstract

Hindered amines and their derived oxidation products, the hindered nitroxyls and hydroxylamines are processing stabilizers and photoantioxidants for poly(vinyl chloride). The evidence suggests that oxidation of the amines occurs very rapidly and completely during mechanooxidation and that the resulting redox couple operates by a catalytic mechanism as described previously for hydrocarbon polymers.
Original languageEnglish
Pages (from-to)6063-6071
Number of pages9
JournalJournal of Applied Polymer Science
Volume32
Issue number7
DOIs
Publication statusPublished - 20 Nov 1986

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Antioxidants
Polyvinyl Chloride
Polyvinyl chlorides
Amines
Hydroxylamines
Stabilization
Vinyl Chloride
Oxidation
Hydrocarbons
Polymers
Processing
nitroxyl
Oxidation-Reduction

Cite this

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Mechanisms of antioxidant action : the role of nitroxyl radicals in the stabilization of PVC . / Adeniyi, Jacob B.; Al-Malaika, Sahar; Scott, Gerald.

In: Journal of Applied Polymer Science, Vol. 32, No. 7, 20.11.1986, p. 6063-6071.

Research output: Contribution to journalArticle

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