Metallocene ethylene-1-octene copolymers

effect of extrusion conditions on thermal oxidation of polymers with different comonomer content

Research output: Contribution to journalArticle

Abstract

Metallocene ethylene-1-octene copolymers having different densities and comonomer content ranging from 11 to 36 wt% (m-LLDPE), and a Ziegler copolymer (z-LLDPE) containing the same level of short-chain branching (SCB) corresponding to one of the m-LLDPE polymers, were subjected to extrusion. The effects of temperature (210-285 °C) and multi-pass extrusions (up to five passes) on the rheological and structural characteristics of these polymers were investigated using melt index and capillary rheometry, along with spectroscopic characterisation of the evolution of various products by FTIR, C-NMR and colour measurements. The aim is to develop a better understanding of the effects of processing variables on the structure and thermal degradation of these polymers. Results from rheology show that both extrusion temperature and the amount of comonomer have a significant influence on the polymer melt thermo-oxidative behaviour. At low to intermediate processing temperatures, all m-LLDPE polymers exhibited similar behaviour with crosslinking reactions dominating their thermal oxidation. By contrast, at higher processing temperatures, the behaviour of the metallocene polymers changed depending on the level of comonomer content: higher SCB gave rise to predominantly chain scission reactions whereas polymers with lower level of SCB continued to be dominated by crosslinking. This temperature dependence was attributed to changes in the different evolution of carbonyl and unsaturated compounds including vinyl, vinylidene and trans-vinylene.
Original languageEnglish
Pages (from-to)2136-2149
Number of pages14
JournalPolymer Degradation and Stability
Volume92
Issue number12
Early online date24 Aug 2007
DOIs
Publication statusPublished - Dec 2007

Fingerprint

Extrusion
copolymers
Polymers
Ethylene
Linear low density polyethylenes
ethylene
Copolymers
Oxidation
oxidation
polymers
Crosslinking
crosslinking
Temperature
Processing
Unsaturated compounds
Carbonyl compounds
Polymer melts
carbonyl compounds
temperature
Rheology

Keywords

  • LLDPE
  • olefin copolymers
  • thermal oxidation
  • melt extrusion

Cite this

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title = "Metallocene ethylene-1-octene copolymers: effect of extrusion conditions on thermal oxidation of polymers with different comonomer content",
abstract = "Metallocene ethylene-1-octene copolymers having different densities and comonomer content ranging from 11 to 36 wt{\%} (m-LLDPE), and a Ziegler copolymer (z-LLDPE) containing the same level of short-chain branching (SCB) corresponding to one of the m-LLDPE polymers, were subjected to extrusion. The effects of temperature (210-285 °C) and multi-pass extrusions (up to five passes) on the rheological and structural characteristics of these polymers were investigated using melt index and capillary rheometry, along with spectroscopic characterisation of the evolution of various products by FTIR, C-NMR and colour measurements. The aim is to develop a better understanding of the effects of processing variables on the structure and thermal degradation of these polymers. Results from rheology show that both extrusion temperature and the amount of comonomer have a significant influence on the polymer melt thermo-oxidative behaviour. At low to intermediate processing temperatures, all m-LLDPE polymers exhibited similar behaviour with crosslinking reactions dominating their thermal oxidation. By contrast, at higher processing temperatures, the behaviour of the metallocene polymers changed depending on the level of comonomer content: higher SCB gave rise to predominantly chain scission reactions whereas polymers with lower level of SCB continued to be dominated by crosslinking. This temperature dependence was attributed to changes in the different evolution of carbonyl and unsaturated compounds including vinyl, vinylidene and trans-vinylene.",
keywords = "LLDPE , olefin copolymers, thermal oxidation, melt extrusion",
author = "Sahar Al-Malaika and X. Peng",
note = "Copyright 2008 Elsevier B.V., All rights reserved.",
year = "2007",
month = "12",
doi = "10.1016/j.polymdegradstab.2007.02.022",
language = "English",
volume = "92",
pages = "2136--2149",
journal = "Polymer Degradation and Stability",
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T1 - Metallocene ethylene-1-octene copolymers

T2 - effect of extrusion conditions on thermal oxidation of polymers with different comonomer content

AU - Al-Malaika, Sahar

AU - Peng, X.

N1 - Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2007/12

Y1 - 2007/12

N2 - Metallocene ethylene-1-octene copolymers having different densities and comonomer content ranging from 11 to 36 wt% (m-LLDPE), and a Ziegler copolymer (z-LLDPE) containing the same level of short-chain branching (SCB) corresponding to one of the m-LLDPE polymers, were subjected to extrusion. The effects of temperature (210-285 °C) and multi-pass extrusions (up to five passes) on the rheological and structural characteristics of these polymers were investigated using melt index and capillary rheometry, along with spectroscopic characterisation of the evolution of various products by FTIR, C-NMR and colour measurements. The aim is to develop a better understanding of the effects of processing variables on the structure and thermal degradation of these polymers. Results from rheology show that both extrusion temperature and the amount of comonomer have a significant influence on the polymer melt thermo-oxidative behaviour. At low to intermediate processing temperatures, all m-LLDPE polymers exhibited similar behaviour with crosslinking reactions dominating their thermal oxidation. By contrast, at higher processing temperatures, the behaviour of the metallocene polymers changed depending on the level of comonomer content: higher SCB gave rise to predominantly chain scission reactions whereas polymers with lower level of SCB continued to be dominated by crosslinking. This temperature dependence was attributed to changes in the different evolution of carbonyl and unsaturated compounds including vinyl, vinylidene and trans-vinylene.

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KW - LLDPE

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