Microstructure and performance investigation of a solid oxide fuel cells based on highly asymmetric YSZ microtubular electrolytes

K. Kanawka, F.D. Grande, Z. Wu, A. Thursfield, D. Ivey, I. Metcalfe, G. Kelsall, K. Li

Research output: Contribution to journalArticle

Abstract

A combined phase inversion and sintering technique was used to fabricate highly asymmetric yttria-stabilized zirconia (YSZ) hollow fibers with a 1.9 mm external diameter and 210 μm total wall thickness. These consisted of a thin (∼10 μm), dense outer layer and a much thicker (∼200 μm) inner layer with finger-like voids. Such highly asymmetric structures formed gas-tight electrolytes and mechanical supports of a microtubular solid oxide fuel cell (SOFC). Nickel oxide−yttria-stabilized zirconia (NiO−YSZ) particles were infused into the pores from alcoholic dispersions and then sintered at 1300 °C, prior to electroless Ni layers being deposited, forming composite anodes. The Ni layer deposited by electroless plating had the function of improving the anodic current collection. Cathodes were deposited by slurry-coating lanthanum strontium manganite particles onto the outer surfaces of YSZ hollow fibers, followed by sintering at 1000 °C and reduction of the anode at 800 °C in a hydrogen environment, completing the fabrication of the microtubular SOFCs. Mechanical strengths of ∼226 MPa were derived from three-point bending tests on hollow fibers sintered at 1450 °C. Initial SOFC performance measurements with 5% H2 as the fuel and air as the oxidant resulted in maximum power densities of 18 mW cm−2 at 800 °C. This low value resulted largely from the discontinuous nature of the electrolessly deposited nickel anode; present work aims to improve its structure and hence SOFC performance.
Original languageEnglish
Pages (from-to)6062-6068
JournalIndustrial and Engineering Chemistry Research
Volume49
Issue number13
DOIs
Publication statusPublished - 28 May 2010

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Yttria stabilized zirconia
Solid oxide fuel cells (SOFC)
Electrolytes
Anodes
Microstructure
Nickel
Fibers
Sintering
Lanthanum
Strontium
Electroless plating
Bending tests
Dispersions
Oxidants
Zirconia
Strength of materials
Hydrogen
Cathodes
Gases
Fabrication

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Kanawka, K. ; Grande, F.D. ; Wu, Z. ; Thursfield, A. ; Ivey, D. ; Metcalfe, I. ; Kelsall, G. ; Li, K. / Microstructure and performance investigation of a solid oxide fuel cells based on highly asymmetric YSZ microtubular electrolytes. In: Industrial and Engineering Chemistry Research. 2010 ; Vol. 49, No. 13. pp. 6062-6068.
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abstract = "A combined phase inversion and sintering technique was used to fabricate highly asymmetric yttria-stabilized zirconia (YSZ) hollow fibers with a 1.9 mm external diameter and 210 μm total wall thickness. These consisted of a thin (∼10 μm), dense outer layer and a much thicker (∼200 μm) inner layer with finger-like voids. Such highly asymmetric structures formed gas-tight electrolytes and mechanical supports of a microtubular solid oxide fuel cell (SOFC). Nickel oxide−yttria-stabilized zirconia (NiO−YSZ) particles were infused into the pores from alcoholic dispersions and then sintered at 1300 °C, prior to electroless Ni layers being deposited, forming composite anodes. The Ni layer deposited by electroless plating had the function of improving the anodic current collection. Cathodes were deposited by slurry-coating lanthanum strontium manganite particles onto the outer surfaces of YSZ hollow fibers, followed by sintering at 1000 °C and reduction of the anode at 800 °C in a hydrogen environment, completing the fabrication of the microtubular SOFCs. Mechanical strengths of ∼226 MPa were derived from three-point bending tests on hollow fibers sintered at 1450 °C. Initial SOFC performance measurements with 5{\%} H2 as the fuel and air as the oxidant resulted in maximum power densities of 18 mW cm−2 at 800 °C. This low value resulted largely from the discontinuous nature of the electrolessly deposited nickel anode; present work aims to improve its structure and hence SOFC performance.",
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Microstructure and performance investigation of a solid oxide fuel cells based on highly asymmetric YSZ microtubular electrolytes. / Kanawka, K.; Grande, F.D.; Wu, Z.; Thursfield, A.; Ivey, D.; Metcalfe, I.; Kelsall, G.; Li, K.

In: Industrial and Engineering Chemistry Research, Vol. 49, No. 13, 28.05.2010, p. 6062-6068.

Research output: Contribution to journalArticle

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T1 - Microstructure and performance investigation of a solid oxide fuel cells based on highly asymmetric YSZ microtubular electrolytes

AU - Kanawka, K.

AU - Grande, F.D.

AU - Wu, Z.

AU - Thursfield, A.

AU - Ivey, D.

AU - Metcalfe, I.

AU - Kelsall, G.

AU - Li, K.

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