Near-field scattering enhancement of perylene based aggregates for random lasing

Zhen Zhen Zhang; Lei Cheng Yin; Xiao Long Xu; Jiang Ying Xia; Kang Xie; Gang Zou; Xiao Juan Zhang; Zhi Jia Hu; Qi Jin Zhang

doi:10.1063/1674-0068/cjcp1807167

Near-field scattering enhancement of perylene based aggregates for random lasing

Zhen Zhen Zhang
, Lei Cheng Yin
, Xiao Long Xu
, Jiang Ying Xia
, Kang Xie
, Gang Zou
, Xiao Juan Zhang
, Zhi Jia Hu^*
, Qi Jin Zhang^*

^*Corresponding author for this work

Aston Institute of Photonic Technologies (AiPT)

CAS Key Laboratory of Soft Matter Chemistry
Hefei University of Technology
Aston University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Strong near-field scattering enhancement (NFSE) of polyhedral oligomeric silsesquioxanes (POSS) nanoparticles (NPs) aggregates is found through physical simulation. An aggregation of N,N'-di-[3-(isobutyl polyhedral oligomeric silsesquioxanes) propyl] perylene diimide (DPP) which possesses POSS as scatteres experimentally performs strong NFSE, which confirms the physical simulation results. Moreover, coherent random laser is triggered from the DPP aggregates in carbon disulfide. It is the NFSE of POSS NPs connected to both ends of DPP through covalent bonds and the NFSE of their aggregation thanks to DPP's aggregation that is responsible for the coherent random laser. So, this work develops a method to improve weak scattering of system through construction of molecules, and opens a road to a variety of novel interdisciplinary investigations, involving molecular designing for disordered photonics.

Original language	English
Pages (from-to)	739-746
Number of pages	8
Journal	Chinese Journal of Chemical Physics
Volume	32
Issue number	6
DOIs	https://doi.org/10.1063/1674-0068/cjcp1807167
Publication status	Published - 27 Dec 2019

Funding

This work was supported by the National Natural Science Foundation of China (No.51673178, No.51273186, No.21574120, No.11874012, No.11404087, and No.11574070), Basic Research Fund for the Central Universities (No.WK2060200012), Science and Technological Fund of Anhui Province for Outstanding Youth (No.1608085J01), Fundamental Research Funds for the Central Universities of China, Postdoctoral Science Foundation (No.2015M571918 and No.2017T100442), the European Union’s Horizon 2020 Research and Innovation Programme under the Marie Sk lodowska-Curie Grant Agreement (No.744817), the Project of State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology (No.18zxhk10).

Keywords

Aggregates
DPP
Isolated particles
Near-field scattering enhancement
Random Laser

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10.1063/1674-0068/cjcp1807167

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@article{92ac40dd9c544eb6abfe2619834123af,

title = "Near-field scattering enhancement of perylene based aggregates for random lasing",

abstract = "Strong near-field scattering enhancement (NFSE) of polyhedral oligomeric silsesquioxanes (POSS) nanoparticles (NPs) aggregates is found through physical simulation. An aggregation of N,N'-di-[3-(isobutyl polyhedral oligomeric silsesquioxanes) propyl] perylene diimide (DPP) which possesses POSS as scatteres experimentally performs strong NFSE, which confirms the physical simulation results. Moreover, coherent random laser is triggered from the DPP aggregates in carbon disulfide. It is the NFSE of POSS NPs connected to both ends of DPP through covalent bonds and the NFSE of their aggregation thanks to DPP's aggregation that is responsible for the coherent random laser. So, this work develops a method to improve weak scattering of system through construction of molecules, and opens a road to a variety of novel interdisciplinary investigations, involving molecular designing for disordered photonics.",

keywords = "Aggregates, DPP, Isolated particles, Near-field scattering enhancement, Random Laser",

author = "Zhang, \{Zhen Zhen\} and Yin, \{Lei Cheng\} and Xu, \{Xiao Long\} and Xia, \{Jiang Ying\} and Kang Xie and Gang Zou and Zhang, \{Xiao Juan\} and Hu, \{Zhi Jia\} and Zhang, \{Qi Jin\}",

year = "2019",

month = dec,

day = "27",

doi = "10.1063/1674-0068/cjcp1807167",

language = "English",

volume = "32",

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journal = "Chinese Journal of Chemical Physics",

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TY - JOUR

T1 - Near-field scattering enhancement of perylene based aggregates for random lasing

AU - Zhang, Zhen Zhen

AU - Yin, Lei Cheng

AU - Xu, Xiao Long

AU - Xia, Jiang Ying

AU - Xie, Kang

AU - Zou, Gang

AU - Zhang, Xiao Juan

AU - Hu, Zhi Jia

AU - Zhang, Qi Jin

PY - 2019/12/27

Y1 - 2019/12/27

N2 - Strong near-field scattering enhancement (NFSE) of polyhedral oligomeric silsesquioxanes (POSS) nanoparticles (NPs) aggregates is found through physical simulation. An aggregation of N,N'-di-[3-(isobutyl polyhedral oligomeric silsesquioxanes) propyl] perylene diimide (DPP) which possesses POSS as scatteres experimentally performs strong NFSE, which confirms the physical simulation results. Moreover, coherent random laser is triggered from the DPP aggregates in carbon disulfide. It is the NFSE of POSS NPs connected to both ends of DPP through covalent bonds and the NFSE of their aggregation thanks to DPP's aggregation that is responsible for the coherent random laser. So, this work develops a method to improve weak scattering of system through construction of molecules, and opens a road to a variety of novel interdisciplinary investigations, involving molecular designing for disordered photonics.

AB - Strong near-field scattering enhancement (NFSE) of polyhedral oligomeric silsesquioxanes (POSS) nanoparticles (NPs) aggregates is found through physical simulation. An aggregation of N,N'-di-[3-(isobutyl polyhedral oligomeric silsesquioxanes) propyl] perylene diimide (DPP) which possesses POSS as scatteres experimentally performs strong NFSE, which confirms the physical simulation results. Moreover, coherent random laser is triggered from the DPP aggregates in carbon disulfide. It is the NFSE of POSS NPs connected to both ends of DPP through covalent bonds and the NFSE of their aggregation thanks to DPP's aggregation that is responsible for the coherent random laser. So, this work develops a method to improve weak scattering of system through construction of molecules, and opens a road to a variety of novel interdisciplinary investigations, involving molecular designing for disordered photonics.

KW - Aggregates

KW - DPP

KW - Isolated particles

KW - Near-field scattering enhancement

KW - Random Laser

UR - https://www.scopus.com/pages/publications/85078234087

UR - https://cps.scitation.org/doi/10.1063/1674-0068/cjcp1807167

U2 - 10.1063/1674-0068/cjcp1807167

DO - 10.1063/1674-0068/cjcp1807167

M3 - Article

AN - SCOPUS:85078234087

SN - 1674-0068

VL - 32

SP - 739

EP - 746

JO - Chinese Journal of Chemical Physics

JF - Chinese Journal of Chemical Physics

IS - 6

ER -

Near-field scattering enhancement of perylene based aggregates for random lasing

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