Non-steady-state living polymerization: A new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature

Hassen Bouchékif*, Marcia I. Philbin, Eamon Colclough, Allan J. Amass

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

Well-defined polyoxetane with low polydispersivity has been synthesized via a novel living polymerisation process using 3-phenoxypropyl 1,4-dioxanium hexafluoroantimonate (3-PPD) as a model of a living "monomeric polyoxetane" initiator, in 1,4-dioxane at 35 °C.

Original languageEnglish
Pages (from-to)3870-3872
Number of pages3
JournalChemical Communications
Issue number30
DOIs
Publication statusPublished - 14 Aug 2005

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Cationic polymerization
Living polymerization
Ring opening polymerization
Polymerization
Chemical activation
Temperature
poly(oxetane)
oxetane
1,4-dioxane

Cite this

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title = "Non-steady-state living polymerization: A new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature",
abstract = "Well-defined polyoxetane with low polydispersivity has been synthesized via a novel living polymerisation process using 3-phenoxypropyl 1,4-dioxanium hexafluoroantimonate (3-PPD) as a model of a living {"}monomeric polyoxetane{"} initiator, in 1,4-dioxane at 35 °C.",
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Non-steady-state living polymerization : A new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature. / Bouchékif, Hassen; Philbin, Marcia I.; Colclough, Eamon; Amass, Allan J.

In: Chemical Communications, No. 30, 14.08.2005, p. 3870-3872.

Research output: Contribution to journalArticle

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AU - Bouchékif, Hassen

AU - Philbin, Marcia I.

AU - Colclough, Eamon

AU - Amass, Allan J.

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