Non-steady-state living polymerization: A new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature

Hassen Bouchékif; Marcia I. Philbin; Eamon Colclough; Allan J. Amass

doi:10.1039/b417076h

Non-steady-state living polymerization: A new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature

Hassen Bouchékif^*
, Marcia I. Philbin
, Eamon Colclough
, Allan J. Amass

^*Corresponding author for this work

Chemical Engineering & Applied Chemistry

Aston University
QinetiQ

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Well-defined polyoxetane with low polydispersivity has been synthesized via a novel living polymerisation process using 3-phenoxypropyl 1,4-dioxanium hexafluoroantimonate (3-PPD) as a model of a living "monomeric polyoxetane" initiator, in 1,4-dioxane at 35 °C.

Original language	English
Pages (from-to)	3870-3872
Number of pages	3
Journal	Chemical Communications
Issue number	30
DOIs	https://doi.org/10.1039/b417076h
Publication status	Published - 14 Aug 2005

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10.1039/b417076h

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title = "Non-steady-state living polymerization: A new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature",

abstract = "Well-defined polyoxetane with low polydispersivity has been synthesized via a novel living polymerisation process using 3-phenoxypropyl 1,4-dioxanium hexafluoroantimonate (3-PPD) as a model of a living {"}monomeric polyoxetane{"} initiator, in 1,4-dioxane at 35 °C.",

author = "Hassen Bouch{\'e}kif and Philbin, \{Marcia I.\} and Eamon Colclough and Amass, \{Allan J.\}",

year = "2005",

month = aug,

day = "14",

doi = "10.1039/b417076h",

language = "English",

pages = "3870--3872",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "30",

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Non-steady-state living polymerization: A new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature. / Bouchékif, Hassen; Philbin, Marcia I.; Colclough, Eamon et al.
In: Chemical Communications, No. 30, 14.08.2005, p. 3870-3872.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Non-steady-state living polymerization

T2 - A new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature

AU - Bouchékif, Hassen

AU - Philbin, Marcia I.

AU - Colclough, Eamon

AU - Amass, Allan J.

PY - 2005/8/14

Y1 - 2005/8/14

N2 - Well-defined polyoxetane with low polydispersivity has been synthesized via a novel living polymerisation process using 3-phenoxypropyl 1,4-dioxanium hexafluoroantimonate (3-PPD) as a model of a living "monomeric polyoxetane" initiator, in 1,4-dioxane at 35 °C.

AB - Well-defined polyoxetane with low polydispersivity has been synthesized via a novel living polymerisation process using 3-phenoxypropyl 1,4-dioxanium hexafluoroantimonate (3-PPD) as a model of a living "monomeric polyoxetane" initiator, in 1,4-dioxane at 35 °C.

UR - https://www.scopus.com/pages/publications/23744440776

U2 - 10.1039/b417076h

DO - 10.1039/b417076h

M3 - Article

AN - SCOPUS:23744440776

SN - 1359-7345

SP - 3870

EP - 3872

JO - Chemical Communications

JF - Chemical Communications

IS - 30

ER -

Non-steady-state living polymerization: A new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature

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