Novel strategic approach for the thermo- and photo-oxidative stabilization of polyolefin/clay nanocomposites

Nadka Tzankova Dintcheva*, Sahar Al-Malaika, Rossella Arrigo, Elisabetta Morici

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

Polyolefin/clay nanocomposites were prepared by melt mixing and their oxidative stability was studied under long-term thermo- and photo-oxidative test conditions in the absence and presence of a modified organo montmorillonite clay (OM-MMt) containing a chemically-bound hindered phenol antioxidant function, (AO)OM-Mt. It was found that nanocomposites based on both polyethylene (PE) and polyethylene-grafted-maleic anhydride (PEgMA) containing the (AO)OM-Mt gave a higher oxidative stability, along with better clay dispersion, compared to analogous PE or PEgMA-based nanocomposites containing an added (free) conventional antioxidant with a similar hindered phenol function (using the commercial hindered phenol Irganox® 1076). These findings can be explained in terms of the ability of the organo-modifier containing the in-built antioxidant function to act locally at the interface between the clay silicate layers and the polymer macromolecules thus contributing to the improved stability of the polymer observed both during long-term thermal- and photo-oxidative treatments.
Original languageEnglish
JournalPolymer Degradation and Stability
Volumein press
Early online date12 Apr 2017
DOIs
Publication statusE-pub ahead of print - 12 Apr 2017

Fingerprint

Polyolefins
antioxidants
Polyethylene
Antioxidants
clays
Polyethylenes
polyethylenes
Nanocomposites
nanocomposites
Clay
Stabilization
stabilization
Phenol
Maleic Anhydrides
phenols
Phenols
Maleic anhydride
anhydrides
Polymers
Bentonite

Bibliographical note

© 2017, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/

Keywords

  • Clay Polymer Nanocomposites (CPN)
  • Hindered phenols
  • Polyolefins
  • Stabilised organo montmorillonite
  • Thermo- and photo- oxidative stabilization

Cite this

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title = "Novel strategic approach for the thermo- and photo-oxidative stabilization of polyolefin/clay nanocomposites",
abstract = "Polyolefin/clay nanocomposites were prepared by melt mixing and their oxidative stability was studied under long-term thermo- and photo-oxidative test conditions in the absence and presence of a modified organo montmorillonite clay (OM-MMt) containing a chemically-bound hindered phenol antioxidant function, (AO)OM-Mt. It was found that nanocomposites based on both polyethylene (PE) and polyethylene-grafted-maleic anhydride (PEgMA) containing the (AO)OM-Mt gave a higher oxidative stability, along with better clay dispersion, compared to analogous PE or PEgMA-based nanocomposites containing an added (free) conventional antioxidant with a similar hindered phenol function (using the commercial hindered phenol Irganox{\circledR} 1076). These findings can be explained in terms of the ability of the organo-modifier containing the in-built antioxidant function to act locally at the interface between the clay silicate layers and the polymer macromolecules thus contributing to the improved stability of the polymer observed both during long-term thermal- and photo-oxidative treatments.",
keywords = "Clay Polymer Nanocomposites (CPN), Hindered phenols, Polyolefins, Stabilised organo montmorillonite, Thermo- and photo- oxidative stabilization",
author = "Dintcheva, {Nadka Tzankova} and Sahar Al-Malaika and Rossella Arrigo and Elisabetta Morici",
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Novel strategic approach for the thermo- and photo-oxidative stabilization of polyolefin/clay nanocomposites. / Dintcheva, Nadka Tzankova; Al-Malaika, Sahar; Arrigo, Rossella; Morici, Elisabetta.

In: Polymer Degradation and Stability, Vol. in press, 12.04.2017.

Research output: Contribution to journalArticle

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AU - Dintcheva, Nadka Tzankova

AU - Al-Malaika, Sahar

AU - Arrigo, Rossella

AU - Morici, Elisabetta

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PY - 2017/4/12

Y1 - 2017/4/12

N2 - Polyolefin/clay nanocomposites were prepared by melt mixing and their oxidative stability was studied under long-term thermo- and photo-oxidative test conditions in the absence and presence of a modified organo montmorillonite clay (OM-MMt) containing a chemically-bound hindered phenol antioxidant function, (AO)OM-Mt. It was found that nanocomposites based on both polyethylene (PE) and polyethylene-grafted-maleic anhydride (PEgMA) containing the (AO)OM-Mt gave a higher oxidative stability, along with better clay dispersion, compared to analogous PE or PEgMA-based nanocomposites containing an added (free) conventional antioxidant with a similar hindered phenol function (using the commercial hindered phenol Irganox® 1076). These findings can be explained in terms of the ability of the organo-modifier containing the in-built antioxidant function to act locally at the interface between the clay silicate layers and the polymer macromolecules thus contributing to the improved stability of the polymer observed both during long-term thermal- and photo-oxidative treatments.

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