One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation

Natalya A. Vorotnikova; Mariya V. Edeleva; Olga G. Kurskaya; Konstantin A. Brylev; Alexander M. Shestopalov; Yuri V. Mironov; Andrew J. Sutherland; Olga A. Efremova; Michael A. Shestopalov

doi:10.1002/pi.5473

One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation

Natalya A. Vorotnikova, Mariya V. Edeleva, Olga G. Kurskaya, Konstantin A. Brylev, Alexander M. Shestopalov, Yuri V. Mironov, Andrew J. Sutherland, Olga A. Efremova^*, Michael A. Shestopalov

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo₆X₈)(NO₃)₆]^2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.

Original language	English
Pages (from-to)	1906-1912
Journal	Polymer International
Volume	66
Issue number	12
Early online date	23 Sept 2017
DOIs	https://doi.org/10.1002/pi.5473
Publication status	Published - Dec 2017

Bibliographical note

Copyright © 2000-2017 by John Wiley & Sons, Inc., or related companies. All rights reserved.

Funding: Grant of the Pre sident of theRussian Federation (grant no. MK-180.2017.3)

Keywords

Copolymer material
Free radical polymerisation
Luminescence
Molybdenum cluster complex

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10.1002/pi.5473

One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free-radical dispersion copolymerisation reaction
Copyright © 2000-2017 by John Wiley & Sons, Inc., or related companies. All rights reserved.
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Vorotnikova, N. A., Edeleva, M. V., Kurskaya, O. G., Brylev, K. A., Shestopalov, A. M., Mironov, Y. V., Sutherland, A. J., Efremova, O. A., & Shestopalov, M. A. (2017). One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation. Polymer International, 66(12), 1906-1912. https://doi.org/10.1002/pi.5473

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title = "One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation",

abstract = "Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.",

keywords = "Copolymer material, Free radical polymerisation, Luminescence, Molybdenum cluster complex",

author = "Vorotnikova, {Natalya A.} and Edeleva, {Mariya V.} and Kurskaya, {Olga G.} and Brylev, {Konstantin A.} and Shestopalov, {Alexander M.} and Mironov, {Yuri V.} and Sutherland, {Andrew J.} and Efremova, {Olga A.} and Shestopalov, {Michael A.}",

note = "Copyright {\textcopyright} 2000-2017 by John Wiley & Sons, Inc., or related companies. All rights reserved. Funding: Grant of the Pre sident of theRussian Federation (grant no. MK-180.2017.3)",

year = "2017",

month = dec,

doi = "10.1002/pi.5473",

language = "English",

volume = "66",

pages = "1906--1912",

journal = "Polymer International",

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Vorotnikova, NA, Edeleva, MV, Kurskaya, OG, Brylev, KA, Shestopalov, AM, Mironov, YV, Sutherland, AJ, Efremova, OA & Shestopalov, MA 2017, 'One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation', Polymer International, vol. 66, no. 12, pp. 1906-1912. https://doi.org/10.1002/pi.5473

One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation. / Vorotnikova, Natalya A.; Edeleva, Mariya V.; Kurskaya, Olga G. et al.
In: Polymer International, Vol. 66, No. 12, 12.2017, p. 1906-1912.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction

T2 - {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation

AU - Vorotnikova, Natalya A.

AU - Edeleva, Mariya V.

AU - Kurskaya, Olga G.

AU - Brylev, Konstantin A.

AU - Shestopalov, Alexander M.

AU - Mironov, Yuri V.

AU - Sutherland, Andrew J.

AU - Efremova, Olga A.

AU - Shestopalov, Michael A.

PY - 2017/12

Y1 - 2017/12

N2 - Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.

AB - Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.

KW - Copolymer material

KW - Free radical polymerisation

KW - Luminescence

KW - Molybdenum cluster complex

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VL - 66

SP - 1906

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JO - Polymer International

JF - Polymer International

IS - 12

ER -

Vorotnikova NA, Edeleva MV, Kurskaya OG, Brylev KA, Shestopalov AM, Mironov YV et al. One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation. Polymer International. 2017 Dec;66(12):1906-1912. Epub 2017 Sept 23. doi: 10.1002/pi.5473

One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation

Abstract

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Keywords

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