One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation

Natalya A. Vorotnikova; Mariya V. Edeleva; Olga G. Kurskaya; Konstantin A. Brylev; Alexander M. Shestopalov; Yuri V. Mironov; Andrew J. Sutherland; Olga A. Efremova; Michael A. Shestopalov

doi:10.1002/pi.5473

One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation

Natalya A. Vorotnikova
, Mariya V. Edeleva
, Olga G. Kurskaya
, Konstantin A. Brylev
, Alexander M. Shestopalov
, Yuri V. Mironov
, Andrew J. Sutherland
, Olga A. Efremova^*
, Michael A. Shestopalov

^*Corresponding author for this work

Nikolaev Institute of Inorganic Chemistry SB RAS
Novosibirsk State University
Research Institute of Experimental and Clinical Medicine
University College Birmingham
University of Hull

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

117 Downloads (Pure)

Abstract

Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo₆X₈)(NO₃)₆]^2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.

Original language	English
Pages (from-to)	1906-1912
Journal	Polymer International
Volume	66
Issue number	12
Early online date	23 Sept 2017
DOIs	https://doi.org/10.1002/pi.5473
Publication status	Published - Dec 2017

Bibliographical note

Copyright © 2000-2017 by John Wiley & Sons, Inc., or related companies. All rights reserved.

Funding: Grant of the Pre sident of theRussian Federation (grant no. MK-180.2017.3)

Keywords

Copolymer material
Free radical polymerisation
Luminescence
Molybdenum cluster complex

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10.1002/pi.5473

One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free-radical dispersion copolymerisation reaction
Copyright © 2000-2017 by John Wiley & Sons, Inc., or related companies. All rights reserved.
Accepted author manuscript, 795 KB

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Vorotnikova, N. A., Edeleva, M. V., Kurskaya, O. G., Brylev, K. A., Shestopalov, A. M., Mironov, Y. V., Sutherland, A. J., Efremova, O. A., & Shestopalov, M. A. (2017). One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation. Polymer International, 66(12), 1906-1912. https://doi.org/10.1002/pi.5473

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title = "One-pot synthesis of \{Mo6 I8 \}4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: \{Mo6 I8 \}4+ -doped polystyrene microspheres via free radical copolymerisation",

abstract = "Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.",

keywords = "Copolymer material, Free radical polymerisation, Luminescence, Molybdenum cluster complex",

author = "Vorotnikova, \{Natalya A.\} and Edeleva, \{Mariya V.\} and Kurskaya, \{Olga G.\} and Brylev, \{Konstantin A.\} and Shestopalov, \{Alexander M.\} and Mironov, \{Yuri V.\} and Sutherland, \{Andrew J.\} and Efremova, \{Olga A.\} and Shestopalov, \{Michael A.\}",

note = "Copyright {\textcopyright} 2000-2017 by John Wiley \& Sons, Inc., or related companies. All rights reserved. Funding: Grant of the Pre sident of theRussian Federation (grant no. MK-180.2017.3)",

year = "2017",

month = dec,

doi = "10.1002/pi.5473",

language = "English",

volume = "66",

pages = "1906--1912",

journal = "Polymer International",

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Vorotnikova, NA, Edeleva, MV, Kurskaya, OG, Brylev, KA, Shestopalov, AM, Mironov, YV, Sutherland, AJ, Efremova, OA & Shestopalov, MA 2017, 'One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation', Polymer International, vol. 66, no. 12, pp. 1906-1912. https://doi.org/10.1002/pi.5473

One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation. / Vorotnikova, Natalya A.; Edeleva, Mariya V.; Kurskaya, Olga G. et al.
In: Polymer International, Vol. 66, No. 12, 12.2017, p. 1906-1912.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction

T2 - {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation

AU - Vorotnikova, Natalya A.

AU - Edeleva, Mariya V.

AU - Kurskaya, Olga G.

AU - Brylev, Konstantin A.

AU - Shestopalov, Alexander M.

AU - Mironov, Yuri V.

AU - Sutherland, Andrew J.

AU - Efremova, Olga A.

AU - Shestopalov, Michael A.

PY - 2017/12

Y1 - 2017/12

N2 - Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.

AB - Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.

KW - Copolymer material

KW - Free radical polymerisation

KW - Luminescence

KW - Molybdenum cluster complex

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DO - 10.1002/pi.5473

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SN - 0959-8103

VL - 66

SP - 1906

EP - 1912

JO - Polymer International

JF - Polymer International

IS - 12

ER -

Vorotnikova NA, Edeleva MV, Kurskaya OG, Brylev KA, Shestopalov AM, Mironov YV et al. One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation. Polymer International. 2017 Dec;66(12):1906-1912. Epub 2017 Sept 23. doi: 10.1002/pi.5473

One-pot synthesis of {Mo6 I8 }4+ -doped polystyrene microspheres via a free radical dispersion copolymerisation reaction: {Mo6 I8 }4+ -doped polystyrene microspheres via free radical copolymerisation

Abstract

Bibliographical note

Keywords

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