Phase behaviour of room temperature ionic liquid solutions: An unusually large co-solvent e3ect in (water + ethanol)

V. Najdanovic-Visak; J.M.S.S. Esperança; L.P.N. Rebelo; M.N. Da Ponte; H.J.R. Guedes; K.R. Seddon; J. Szydlowski

doi:10.1039/b201723g

Phase behaviour of room temperature ionic liquid solutions: An unusually large co-solvent e3ect in (water + ethanol)

V. Najdanovic-Visak
, J.M.S.S. Esperança
, L.P.N. Rebelo
, M.N. Da Ponte
, H.J.R. Guedes
, K.R. Seddon
, J. Szydlowski

Research output: Contribution to journal › Article › peer-review

232 Citations (Scopus)

Abstract

A surprising mixed solvent effect, both in its magnitude and direction, has been found in the phase diagram of the ternary mixture of ([C4mim][PF6] + (water + ethanol)). For a molar ratio of 1∶1 of water to ethanol, the co-solvent effect in the near-critical demixing temperature can be as large as 80 K.

Original language	English
Pages (from-to)	1701-1703
Journal	Physical Chemistry Chemical Physics
Volume	4
DOIs	https://doi.org/10.1039/b201723g
Publication status	Published - 2 Apr 2002

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abstract = "A surprising mixed solvent effect, both in its magnitude and direction, has been found in the phase diagram of the ternary mixture of ([C4mim][PF6] + (water + ethanol)). For a molar ratio of 1∶1 of water to ethanol, the co-solvent effect in the near-critical demixing temperature can be as large as 80 K.",

author = "V. Najdanovic-Visak and J.M.S.S. Esperan{\c c}a and L.P.N. Rebelo and \{Da Ponte\}, M.N. and H.J.R. Guedes and K.R. Seddon and J. Szydlowski",

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AU - Najdanovic-Visak, V.

AU - Esperança, J.M.S.S.

AU - Rebelo, L.P.N.

AU - Da Ponte, M.N.

AU - Guedes, H.J.R.

AU - Seddon, K.R.

AU - Szydlowski, J.

PY - 2002/4/2

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N2 - A surprising mixed solvent effect, both in its magnitude and direction, has been found in the phase diagram of the ternary mixture of ([C4mim][PF6] + (water + ethanol)). For a molar ratio of 1∶1 of water to ethanol, the co-solvent effect in the near-critical demixing temperature can be as large as 80 K.

AB - A surprising mixed solvent effect, both in its magnitude and direction, has been found in the phase diagram of the ternary mixture of ([C4mim][PF6] + (water + ethanol)). For a molar ratio of 1∶1 of water to ethanol, the co-solvent effect in the near-critical demixing temperature can be as large as 80 K.

UR - https://www.scopus.com/pages/publications/0036255113

UR - https://pubs.rsc.org/en/content/articlelanding/2002/CP/b201723g#!divAbstract

U2 - 10.1039/b201723g

DO - 10.1039/b201723g

M3 - Article

SN - 1463-9076

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SP - 1701

EP - 1703

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

ER -

Phase behaviour of room temperature ionic liquid solutions: An unusually large co-solvent e3ect in (water + ethanol)

Abstract

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