Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

Olga A. Efremova, Konstantin A. Brylev, Yuri A. Vorotnikov, Lucie Vejsadová, Michael A. Shestopalov, Gwen F. Chimonides, Petr Mikes, Paul D. Topham, Sung-Jin Kim, Noboru Kitamura, Andrew J. Sutherland

Research output: Contribution to journalArticle

Abstract

Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo6I8}(OTs)6]2- (where OTs- is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)2[{Mo6I8}(OTs)6], where dMDAEMA+ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.

LanguageEnglish
Pages497-503
Number of pages7
JournalJournal of Materials Chemistry C
Volume4
Issue number3
Early online date14 Dec 2015
DOIs
Publication statusPublished - 21 Jan 2016

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Molybdenum
Polymethyl Methacrylate
Metals
Transparency
Methacrylates
Hybrid materials
Polymethyl methacrylates
Copolymerization
Cations
Photoluminescence
Positive ions
Ions

Bibliographical note

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

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Efremova, O. A., Brylev, K. A., Vorotnikov, Y. A., Vejsadová, L., Shestopalov, M. A., Chimonides, G. F., ... Sutherland, A. J. (2016). Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex. Journal of Materials Chemistry C, 4(3), 497-503. https://doi.org/10.1039/c5tc03204k
Efremova, Olga A. ; Brylev, Konstantin A. ; Vorotnikov, Yuri A. ; Vejsadová, Lucie ; Shestopalov, Michael A. ; Chimonides, Gwen F. ; Mikes, Petr ; Topham, Paul D. ; Kim, Sung-Jin ; Kitamura, Noboru ; Sutherland, Andrew J. / Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex. In: Journal of Materials Chemistry C. 2016 ; Vol. 4, No. 3. pp. 497-503.
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Efremova, OA, Brylev, KA, Vorotnikov, YA, Vejsadová, L, Shestopalov, MA, Chimonides, GF, Mikes, P, Topham, PD, Kim, S-J, Kitamura, N & Sutherland, AJ 2016, 'Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex' Journal of Materials Chemistry C, vol. 4, no. 3, pp. 497-503. https://doi.org/10.1039/c5tc03204k

Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex. / Efremova, Olga A.; Brylev, Konstantin A.; Vorotnikov, Yuri A.; Vejsadová, Lucie; Shestopalov, Michael A.; Chimonides, Gwen F.; Mikes, Petr; Topham, Paul D.; Kim, Sung-Jin; Kitamura, Noboru; Sutherland, Andrew J.

In: Journal of Materials Chemistry C, Vol. 4, No. 3, 21.01.2016, p. 497-503.

Research output: Contribution to journalArticle

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AU - Vejsadová, Lucie

AU - Shestopalov, Michael A.

AU - Chimonides, Gwen F.

AU - Mikes, Petr

AU - Topham, Paul D.

AU - Kim, Sung-Jin

AU - Kitamura, Noboru

AU - Sutherland, Andrew J.

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Efremova OA, Brylev KA, Vorotnikov YA, Vejsadová L, Shestopalov MA, Chimonides GF et al. Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex. Journal of Materials Chemistry C. 2016 Jan 21;4(3):497-503. https://doi.org/10.1039/c5tc03204k