Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

Olga A. Efremova; Konstantin A. Brylev; Yuri A. Vorotnikov; Lucie Vejsadová; Michael A. Shestopalov; Gwen F. Chimonides; Petr Mikes; Paul D. Topham; Sung-Jin Kim; Noboru Kitamura; Andrew J. Sutherland

doi:10.1039/c5tc03204k

Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

Olga A. Efremova^*, Konstantin A. Brylev, Yuri A. Vorotnikov, Lucie Vejsadová, Michael A. Shestopalov, Gwen F. Chimonides, Petr Mikes, Paul D. Topham, Sung-Jin Kim, Noboru Kitamura, Andrew J. Sutherland

^*Corresponding author for this work

Chemical Engineering & Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo₆I₈}(OTs)₆]^2- (where OTs^- is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)₂[{Mo₆I₈}(OTs)₆], where dMDAEMA⁺ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.

Original language	English
Pages (from-to)	497-503
Number of pages	7
Journal	Journal of Materials Chemistry C
Volume	4
Issue number	3
Early online date	14 Dec 2015
DOIs	https://doi.org/10.1039/c5tc03204k
Publication status	Published - 21 Jan 2016

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Photoluminescent materials based on PMMA
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Efremova, O. A., Brylev, K. A., Vorotnikov, Y. A., Vejsadová, L., Shestopalov, M. A., Chimonides, G. F., Mikes, P., Topham, P. D., Kim, S.-J., Kitamura, N., & Sutherland, A. J. (2016). Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex. Journal of Materials Chemistry C, 4(3), 497-503. https://doi.org/10.1039/c5tc03204k

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abstract = "Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo6I8}(OTs)6]2- (where OTs- is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)2[{Mo6I8}(OTs)6], where dMDAEMA+ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.",

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AU - Efremova, Olga A.

AU - Brylev, Konstantin A.

AU - Vorotnikov, Yuri A.

AU - Vejsadová, Lucie

AU - Shestopalov, Michael A.

AU - Chimonides, Gwen F.

AU - Mikes, Petr

AU - Topham, Paul D.

AU - Kim, Sung-Jin

AU - Kitamura, Noboru

AU - Sutherland, Andrew J.

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AB - Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo6I8}(OTs)6]2- (where OTs- is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)2[{Mo6I8}(OTs)6], where dMDAEMA+ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.

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Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

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