Quantitative interpretation of diffusion-ordered NMR spectra: can we rationalize small molecule diffusion coefficients?

Robert Evans, Zhaoxia Deng, Alexandria K. Rogerson, Andy S. McLachlan, Jeff J. Richards, Mathias Nilsson, Gareth A. Morris

Research output: Contribution to journalArticle

Abstract

Appealingly simple: A new method is described that allows the diffusion coefficient of a small molecule to be estimated given only the molecular weight and the viscosity of the solvent used. This method makes possible the quantitative interpretation of the diffusion domain of diffusion-ordered NMR spectra (see picture).
LanguageEnglish
Pages3199-3202
Number of pages4
JournalAngewandte Chemie
Volume52
Issue number11
Early online date31 Jan 2013
DOIs
Publication statusPublished - 11 Mar 2013

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Nuclear magnetic resonance
Molecules
Molecular weight
Viscosity

Keywords

  • analytical methods
  • diffusion
  • diffusion-ordered spectroscopy
  • molecular weight
  • NMR spectroscopy

Cite this

Evans, R., Deng, Z., Rogerson, A. K., McLachlan, A. S., Richards, J. J., Nilsson, M., & Morris, G. A. (2013). Quantitative interpretation of diffusion-ordered NMR spectra: can we rationalize small molecule diffusion coefficients? Angewandte Chemie, 52(11), 3199-3202. https://doi.org/10.1002/anie.201207403
Evans, Robert ; Deng, Zhaoxia ; Rogerson, Alexandria K. ; McLachlan, Andy S. ; Richards, Jeff J. ; Nilsson, Mathias ; Morris, Gareth A. / Quantitative interpretation of diffusion-ordered NMR spectra : can we rationalize small molecule diffusion coefficients?. In: Angewandte Chemie. 2013 ; Vol. 52, No. 11. pp. 3199-3202.
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Quantitative interpretation of diffusion-ordered NMR spectra : can we rationalize small molecule diffusion coefficients? / Evans, Robert; Deng, Zhaoxia; Rogerson, Alexandria K.; McLachlan, Andy S.; Richards, Jeff J.; Nilsson, Mathias; Morris, Gareth A.

In: Angewandte Chemie, Vol. 52, No. 11, 11.03.2013, p. 3199-3202.

Research output: Contribution to journalArticle

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