Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd

Adam F. Lee; Christine V. Ellis; James N. Naughton; Mark A. Newton; Christopher M.A. Parlett; Karen Wilson

doi:10.1021/ja200684f

Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd

Adam F. Lee
, Christine V. Ellis
, James N. Naughton
, Mark A. Newton
, Christopher M.A. Parlett
, Karen Wilson

University of York
Cardiff University
European Synchrotron Radiation Facility

Research output: Contribution to journal › Article › peer-review

93 Citations (Scopus)

Abstract

Synchronous, time-resolved DRIFTS/MS/XAS cycling studies of the vapor-phase selective aerobic oxidation of crotyl alcohol over nanoparticulate Pd have revealed surface oxide as the desired catalytically active phase, with dynamic, reaction-induced Pd redox processes controlling selective versus combustion pathways.

Original language	English
Pages (from-to)	5724-5727
Number of pages	4
Journal	Journal of American Chemical Society
Volume	133
Issue number	15
DOIs	https://doi.org/10.1021/ja200684f
Publication status	Published - 25 Mar 2011

Bibliographical note

We thankthe EPSRC (EP/E046754/1,EP/G007594/2) for financial support, a Leadership Fellowship (A.F.L.), and studentship support (C.V.E., J.N.N., and C.M.A.P.) and the ESRF for beamtime (CH2432). A.F.L. thanks Miss Carly J. Broderick for invaluable support.

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10.1021/ja200684f

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title = "Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd",

abstract = "Synchronous, time-resolved DRIFTS/MS/XAS cycling studies of the vapor-phase selective aerobic oxidation of crotyl alcohol over nanoparticulate Pd have revealed surface oxide as the desired catalytically active phase, with dynamic, reaction-induced Pd redox processes controlling selective versus combustion pathways.",

author = "Lee, \{Adam F.\} and Ellis, \{Christine V.\} and Naughton, \{James N.\} and Newton, \{Mark A.\} and Parlett, \{Christopher M.A.\} and Karen Wilson",

note = "We thankthe EPSRC (EP/E046754/1,EP/G007594/2) for financial support, a Leadership Fellowship (A.F.L.), and studentship support (C.V.E., J.N.N., and C.M.A.P.) and the ESRF for beamtime (CH2432). A.F.L. thanks Miss Carly J. Broderick for invaluable support.",

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doi = "10.1021/ja200684f",

language = "English",

volume = "133",

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T1 - Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd

AU - Lee, Adam F.

AU - Ellis, Christine V.

AU - Naughton, James N.

AU - Newton, Mark A.

AU - Parlett, Christopher M.A.

AU - Wilson, Karen

N1 - We thankthe EPSRC (EP/E046754/1,EP/G007594/2) for financial support, a Leadership Fellowship (A.F.L.), and studentship support (C.V.E., J.N.N., and C.M.A.P.) and the ESRF for beamtime (CH2432). A.F.L. thanks Miss Carly J. Broderick for invaluable support.

PY - 2011/3/25

Y1 - 2011/3/25

N2 - Synchronous, time-resolved DRIFTS/MS/XAS cycling studies of the vapor-phase selective aerobic oxidation of crotyl alcohol over nanoparticulate Pd have revealed surface oxide as the desired catalytically active phase, with dynamic, reaction-induced Pd redox processes controlling selective versus combustion pathways.

AB - Synchronous, time-resolved DRIFTS/MS/XAS cycling studies of the vapor-phase selective aerobic oxidation of crotyl alcohol over nanoparticulate Pd have revealed surface oxide as the desired catalytically active phase, with dynamic, reaction-induced Pd redox processes controlling selective versus combustion pathways.

UR - https://www.scopus.com/pages/publications/79954541156

UR - http://pubs.acs.org/doi/abs/10.1021/ja200684f

U2 - 10.1021/ja200684f

DO - 10.1021/ja200684f

M3 - Article

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AN - SCOPUS:79954541156

SN - 0002-7863

VL - 133

SP - 5724

EP - 5727

JO - Journal of American Chemical Society

JF - Journal of American Chemical Society

IS - 15

ER -

Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd

Abstract

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