Redox-controlled crotyl alcohol selective oxidation: in situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS

Christine V. Gaskell; Christopher M.A. Parlett; Mark A. Newton; Karen Wilson; Adam F. Lee

doi:10.1021/cs300445y

Redox-controlled crotyl alcohol selective oxidation: in situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS

Christine V. Gaskell
, Christopher M.A. Parlett
, Mark A. Newton
, Karen Wilson
, Adam F. Lee

European Synchrotron Radiation Facility
Cardiff University

Research output: Contribution to journal › Letter, comment/opinion or interview › peer-review

22 Citations (Scopus)

Abstract

In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.

Original language	English
Pages (from-to)	2242-2246
Number of pages	5
Journal	ACS Catalysis
Volume	2
Issue number	11
Early online date	17 Sept 2012
DOIs	https://doi.org/10.1021/cs300445y
Publication status	Published - 2 Nov 2012

Keywords

palladium
kinetics
XAS
selective oxidation
alcohol

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10.1021/cs300445y

Cite this

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title = "Redox-controlled crotyl alcohol selective oxidation: in situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS",

abstract = "In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.",

keywords = "palladium, kinetics, XAS, selective oxidation, alcohol",

author = "Gaskell, \{Christine V.\} and Parlett, \{Christopher M.A.\} and Newton, \{Mark A.\} and Karen Wilson and Lee, \{Adam F.\}",

year = "2012",

month = nov,

day = "2",

doi = "10.1021/cs300445y",

language = "English",

volume = "2",

pages = "2242--2246",

journal = "ACS Catalysis",

issn = "2155-5435",

publisher = "American Chemical Society",

number = "11",

}

Redox-controlled crotyl alcohol selective oxidation: in situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS. / Gaskell, Christine V.; Parlett, Christopher M.A.; Newton, Mark A. et al.
In: ACS Catalysis, Vol. 2, No. 11, 02.11.2012, p. 2242-2246.

Research output: Contribution to journal › Letter, comment/opinion or interview › peer-review

TY - JOUR

T1 - Redox-controlled crotyl alcohol selective oxidation

T2 - in situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS

AU - Gaskell, Christine V.

AU - Parlett, Christopher M.A.

AU - Newton, Mark A.

AU - Wilson, Karen

AU - Lee, Adam F.

PY - 2012/11/2

Y1 - 2012/11/2

N2 - In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.

AB - In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.

KW - palladium

KW - kinetics

KW - XAS

KW - selective oxidation

KW - alcohol

UR - https://www.scopus.com/pages/publications/84868365648

UR - http://pubs.acs.org/doi/abs/10.1021/cs300445y

U2 - 10.1021/cs300445y

DO - 10.1021/cs300445y

M3 - Letter, comment/opinion or interview

AN - SCOPUS:84868365648

SN - 2155-5435

VL - 2

SP - 2242

EP - 2246

JO - ACS Catalysis

JF - ACS Catalysis

IS - 11

ER -

Redox-controlled crotyl alcohol selective oxidation: in situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS

Abstract

Keywords

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