Selective functionalisation of Re6 cluster anionic units: from hexa-hydroxo [Re6Q8(OH)6]4− (Q = S, Se) to neutral trans-[Re6Q8L4L′2] hybrid building blocks

Frédérick Dorson, Yann Molard, Stéphane Cordier, Bruno Fabre, Olga Efremova, David Rondeau, Yuri Mironov, Viorel Cîrcu, Nikolay Naumov, Christiane Perrin

Research output: Contribution to journalArticle

Abstract

The reaction of [Re6Q8(OH)6]4- (Q = S, Se) with p-tertbutylpyridine (TBP) in water leads to neutral trans-[Re6Q8(TBP)4(OH)2] whose hydroxyl reactivity with carboxylic acid and TBP exchange reaction with functional pyridine have been investigated.
Original languageEnglish
Pages (from-to)1297-1299
Number of pages3
JournalDalton Transactions
Volume2009
Issue number8
DOIs
Publication statusPublished - 28 Feb 2009

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