Solubility and phase behavior of binary systems containing salts based on transitional metals

M.E. Zakrzewska, A.B. Paninho, M.F. Môlho, A.V.M. Nunes, C.A.M. Afonso, A.A. Rosatella, J.M. Lopes, V. Najdanovic-Visak

Research output: Contribution to journalArticle

Abstract

Tri(1-ethyl-3-methylimidazolium) gadolinium hexachloride ([emim]3[GdCl6]), tri(1-butyl-3-methylimidazolium) hexagadolinium chloride ([bmim]3[GdCl6]), di(tetramethylammonium) manganese tetrachloride ([TMA]2[MnCl4]) and cholinium tetrachloroferrate ([Chol][FeCl4]) were synthetized and their solubility in water, ethanol, 1-propanol and 1-butanol were determined as a function of temperature. Activity coefficients were calculated and their comparison with ideal solutions is discussed. The experimental data were correlated successfully by means of the semi-empirical Grant equation. In addition, melting point depression effect of high pressure carbon dioxide was studied.
Original languageEnglish
Pages (from-to)123-127
JournalJournal of Chemical Thermodynamics
Volume63
DOIs
Publication statusPublished - 1 Aug 2013

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1-Propanol
tetrachlorides
1-Butanol
Gadolinium
Activity coefficients
Propanol
Phase behavior
Manganese
gadolinium
Butenes
Carbon Dioxide
melting points
Melting point
carbon dioxide
manganese
Carbon dioxide
Ethanol
ethyl alcohol
solubility
Solubility

Cite this

Zakrzewska, M. E., Paninho, A. B., Môlho, M. F., Nunes, A. V. M., Afonso, C. A. M., Rosatella, A. A., ... Najdanovic-Visak, V. (2013). Solubility and phase behavior of binary systems containing salts based on transitional metals. Journal of Chemical Thermodynamics, 63, 123-127. https://doi.org/10.1016/j.jct.2013.03.014
Zakrzewska, M.E. ; Paninho, A.B. ; Môlho, M.F. ; Nunes, A.V.M. ; Afonso, C.A.M. ; Rosatella, A.A. ; Lopes, J.M. ; Najdanovic-Visak, V. / Solubility and phase behavior of binary systems containing salts based on transitional metals. In: Journal of Chemical Thermodynamics. 2013 ; Vol. 63. pp. 123-127.
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Zakrzewska, ME, Paninho, AB, Môlho, MF, Nunes, AVM, Afonso, CAM, Rosatella, AA, Lopes, JM & Najdanovic-Visak, V 2013, 'Solubility and phase behavior of binary systems containing salts based on transitional metals', Journal of Chemical Thermodynamics, vol. 63, pp. 123-127. https://doi.org/10.1016/j.jct.2013.03.014

Solubility and phase behavior of binary systems containing salts based on transitional metals. / Zakrzewska, M.E.; Paninho, A.B.; Môlho, M.F.; Nunes, A.V.M.; Afonso, C.A.M.; Rosatella, A.A.; Lopes, J.M.; Najdanovic-Visak, V.

In: Journal of Chemical Thermodynamics, Vol. 63, 01.08.2013, p. 123-127.

Research output: Contribution to journalArticle

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AU - Paninho, A.B.

AU - Môlho, M.F.

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AU - Afonso, C.A.M.

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AU - Lopes, J.M.

AU - Najdanovic-Visak, V.

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Zakrzewska ME, Paninho AB, Môlho MF, Nunes AVM, Afonso CAM, Rosatella AA et al. Solubility and phase behavior of binary systems containing salts based on transitional metals. Journal of Chemical Thermodynamics. 2013 Aug 1;63:123-127. https://doi.org/10.1016/j.jct.2013.03.014