Spin transition of 1D, 2D and 3D iron(II) complex polymers - the tug-of-war between elastic interaction and a shock-absorber effect

Petra J. van Koningsbruggen, Matthias Grunert, Peter Weinberger

Research output: Contribution to journalArticle

Abstract

The structures of linear chain Fe(II) spin-crossover compounds of α,β- and α,ω-bis (tetrazol-1-yl)alkane type ligands are described in relation to their magnetic properties. The first threefold interlocked 3-D catenane Fe(II) spin-transition system, [μ-tris(1,4-bis(tetrazol-1-yl)butane-N1,N1′) iron(II)] bis(perchlorate), will be discussed. An analysis is made among the structures and the cooperativity of the spin-crossover behaviour of polynuclear Fe(II) spin-transition materials.
Original languageEnglish
Pages (from-to)183-198
Number of pages16
JournalMonatshefte für Chemier
Volume134
Issue number2
DOIs
Publication statusPublished - Jan 2003

Fingerprint

Shock absorbers
Alkanes
Magnetic properties
Polymers
Iron
Ligands
perchlorate
butane
catenane

Keywords

  • spin-crossover
  • high-spin
  • low-spin
  • Fe(II)
  • chain catenane
  • tetrazole
  • polynuclear compounds

Cite this

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title = "Spin transition of 1D, 2D and 3D iron(II) complex polymers - the tug-of-war between elastic interaction and a shock-absorber effect",
abstract = "The structures of linear chain Fe(II) spin-crossover compounds of α,β- and α,ω-bis (tetrazol-1-yl)alkane type ligands are described in relation to their magnetic properties. The first threefold interlocked 3-D catenane Fe(II) spin-transition system, [μ-tris(1,4-bis(tetrazol-1-yl)butane-N1,N1′) iron(II)] bis(perchlorate), will be discussed. An analysis is made among the structures and the cooperativity of the spin-crossover behaviour of polynuclear Fe(II) spin-transition materials.",
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author = "{van Koningsbruggen}, {Petra J.} and Matthias Grunert and Peter Weinberger",
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year = "2003",
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Spin transition of 1D, 2D and 3D iron(II) complex polymers - the tug-of-war between elastic interaction and a shock-absorber effect. / van Koningsbruggen, Petra J.; Grunert, Matthias; Weinberger, Peter.

In: Monatshefte für Chemier, Vol. 134, No. 2, 01.2003, p. 183-198.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Spin transition of 1D, 2D and 3D iron(II) complex polymers - the tug-of-war between elastic interaction and a shock-absorber effect

AU - van Koningsbruggen, Petra J.

AU - Grunert, Matthias

AU - Weinberger, Peter

N1 - Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2003/1

Y1 - 2003/1

N2 - The structures of linear chain Fe(II) spin-crossover compounds of α,β- and α,ω-bis (tetrazol-1-yl)alkane type ligands are described in relation to their magnetic properties. The first threefold interlocked 3-D catenane Fe(II) spin-transition system, [μ-tris(1,4-bis(tetrazol-1-yl)butane-N1,N1′) iron(II)] bis(perchlorate), will be discussed. An analysis is made among the structures and the cooperativity of the spin-crossover behaviour of polynuclear Fe(II) spin-transition materials.

AB - The structures of linear chain Fe(II) spin-crossover compounds of α,β- and α,ω-bis (tetrazol-1-yl)alkane type ligands are described in relation to their magnetic properties. The first threefold interlocked 3-D catenane Fe(II) spin-transition system, [μ-tris(1,4-bis(tetrazol-1-yl)butane-N1,N1′) iron(II)] bis(perchlorate), will be discussed. An analysis is made among the structures and the cooperativity of the spin-crossover behaviour of polynuclear Fe(II) spin-transition materials.

KW - spin-crossover

KW - high-spin

KW - low-spin

KW - Fe(II)

KW - chain catenane

KW - tetrazole

KW - polynuclear compounds

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U2 - 10.1007/s00706-002-0492-9

DO - 10.1007/s00706-002-0492-9

M3 - Article

VL - 134

SP - 183

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JO - Monatshefte für Chemier

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