TY - JOUR
T1 - Spin transition of 1D, 2D and 3D iron(II) complex polymers - the tug-of-war between elastic interaction and a shock-absorber effect
AU - van Koningsbruggen, Petra J.
AU - Grunert, Matthias
AU - Weinberger, Peter
N1 - Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2003/1
Y1 - 2003/1
N2 - The structures of linear chain Fe(II) spin-crossover compounds of α,β- and α,ω-bis (tetrazol-1-yl)alkane type ligands are described in relation to their magnetic properties. The first threefold interlocked 3-D catenane Fe(II) spin-transition system, [μ-tris(1,4-bis(tetrazol-1-yl)butane-N1,N1′) iron(II)] bis(perchlorate), will be discussed. An analysis is made among the structures and the cooperativity of the spin-crossover behaviour of polynuclear Fe(II) spin-transition materials.
AB - The structures of linear chain Fe(II) spin-crossover compounds of α,β- and α,ω-bis (tetrazol-1-yl)alkane type ligands are described in relation to their magnetic properties. The first threefold interlocked 3-D catenane Fe(II) spin-transition system, [μ-tris(1,4-bis(tetrazol-1-yl)butane-N1,N1′) iron(II)] bis(perchlorate), will be discussed. An analysis is made among the structures and the cooperativity of the spin-crossover behaviour of polynuclear Fe(II) spin-transition materials.
KW - spin-crossover
KW - high-spin
KW - low-spin
KW - Fe(II)
KW - chain catenane
KW - tetrazole
KW - polynuclear compounds
UR - http://www.scopus.com/inward/record.url?scp=0037762247&partnerID=8YFLogxK
UR - http://link.springer.com/article/10.1007%2Fs00706-002-0492-9
U2 - 10.1007/s00706-002-0492-9
DO - 10.1007/s00706-002-0492-9
M3 - Article
AN - SCOPUS:0037762247
SN - 0026-9247
VL - 134
SP - 183
EP - 198
JO - Monatshefte für Chemier
JF - Monatshefte für Chemier
IS - 2
ER -