SQUID magnetometry as a tool for following a clock reaction in solution

Robert Evans, Kevin B. Henbest, Michael A. Hayward, Melanie M. Britton, Kiminori Maeda, Christiane R. Timmel

Research output: Contribution to journalArticle

Abstract

SQUID magnetometry, normally used to characterise the properties of solids, was used to follow a clock reaction in solution, namely the auto-catalytic oxidation of [Co(ii)EDTA] by HO, in real time and it was shown that, in combination with other methods (e.g., magnetic resonance proton relaxation studies and UV-vis absorption analysis), SQUID magnetometry can be a powerful method in elucidating and interpreting the time-profile of chemical reactions so as long as reactants, intermediates and products have suitably large differences in their respective magnetic susceptibilities.
Original languageEnglish
Pages (from-to)2467-2469
Number of pages3
JournalDalton Transactions
Volume2009
Issue number14
Early online date18 Feb 2009
DOIs
Publication statusPublished - 2009

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Evans, R., Henbest, K. B., Hayward, M. A., Britton, M. M., Maeda, K., & Timmel, C. R. (2009). SQUID magnetometry as a tool for following a clock reaction in solution. Dalton Transactions, 2009(14), 2467-2469. https://doi.org/10.1039/b819977a