Stable Formamidinium‐Based Centimeter Long Two‐Dimensional Lead Halide Perovskite Single‐Crystal for Long‐Live Optoelectronic Applications

Rajesh Kumar Ulaganathan; Raghavan Chinnambedu Murugesan; Chang‐yu Lin; Ambika Subramanian; Wei‐liang Chen; Yu‐ming Chang; Alex Rozhin; Raman Sankar

doi:10.1002/adfm.202112277

Stable Formamidinium‐Based Centimeter Long Two‐Dimensional Lead Halide Perovskite Single‐Crystal for Long‐Live Optoelectronic Applications

Rajesh Kumar Ulaganathan, Raghavan Chinnambedu Murugesan, Chang‐yu Lin, Ambika Subramanian, Wei‐liang Chen, Yu‐ming Chang, Alex Rozhin, Raman Sankar

Research output: Contribution to journal › Article › peer-review

Abstract

Solution-processable 2D metal-halide perovskites are highly promising for cost-effective optoelectronic applications due to their intrinsic multiquantum well structure. However, the lack of stability is still a major obstacle in the use of this class of materials in practical devices. Here, the authors demonstrate the stable optoelectronic properties using formamidinium (FA)-based centimeter-long 2D perovskite (BA)₂FAPb₂I₇ high-quality single-crystal controlled by the thickness of two perovskite layers. The large area single-crystal exhibits good crystallinity, phase purity, and spectral uniformity. Moreover, the (BA)₂FAPb₂I₇ single-crystal shows excellent stability at open atmospheric conditions when compared to methylammonium (MA)-based (BA)₂MAPb₂I₇ counterparts. The photodetectors fabricated using 2D perovskite single-crystal on the rigid Si/SiO2 substrate reveal high photoresponsivity (Rλ)(≈5 A W⁻¹), the fast response time (<20 ms), specific detectivity (D*) (≈3.5 × 10¹¹ Jones), and excellent durability under 488 nm laser illumination. The Rλ and D* values are obtained from the (BA)₂FAPb₂I₇₇ single-crystal 25 times and three orders magnitudes, respectively, higher than the (BA)₂MAPb₂I₇single-crystal. Additionally, the perovskite material on flexible polymer substrate reveals good photo-sensing properties in both bending and nonbending states.

Original language	English
Article number	2112277
Journal	Advanced Functional Materials
Early online date	31 Dec 2021
DOIs	https://doi.org/10.1002/adfm.202112277
Publication status	E-pub ahead of print - 31 Dec 2021

Bibliographical note

This is the peer reviewed version of the following article: 'Ulaganathan, R. K., Murugesan, R. C., Lin, C.-Y., et al (2021). Stable Formamidinium-Based Centimeter Long Two-Dimensional Lead Halide Perovskite Single-Crystal for Long-Live Optoelectronic Applications. Advanced Functional Materials', which has been published in final form at [https://doi.org/10.1002/adfm.202112277]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.

Keywords

ambient stability
flexible electronics
photoresponsivity
specific detectivity
two-dimensional perovskites

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10.1002/adfm.202112277

Uluganathan et al Advanced Functional Materials Stable Formamidinium
This is the peer reviewed version of the following article: 'Ulaganathan, Murugesan, Lin et al (2021). Stable Formamidinium-Based Centimeter Long Two-Dimensional Lead Halide Perovskite Single-Crystal for Long-Live Optoelectronic Applications. Advanced Functional Materials', which has been published in final form at [https://doi.org/10.1002/adfm.202112277]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.
Accepted author manuscript, 1.95 MBLicence: Unspecified

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Ulaganathan, R. K., Murugesan, R. C., Lin, C., Subramanian, A., Chen, W., Chang, Y., Rozhin, A., & Sankar, R. (2021). Stable Formamidinium‐Based Centimeter Long Two‐Dimensional Lead Halide Perovskite Single‐Crystal for Long‐Live Optoelectronic Applications. Advanced Functional Materials, Article 2112277. Advance online publication. https://doi.org/10.1002/adfm.202112277

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abstract = "Solution-processable 2D metal-halide perovskites are highly promising for cost-effective optoelectronic applications due to their intrinsic multiquantum well structure. However, the lack of stability is still a major obstacle in the use of this class of materials in practical devices. Here, the authors demonstrate the stable optoelectronic properties using formamidinium (FA)-based centimeter-long 2D perovskite (BA)2FAPb2I7 high-quality single-crystal controlled by the thickness of two perovskite layers. The large area single-crystal exhibits good crystallinity, phase purity, and spectral uniformity. Moreover, the (BA)2FAPb2I7 single-crystal shows excellent stability at open atmospheric conditions when compared to methylammonium (MA)-based (BA)2MAPb2I7 counterparts. The photodetectors fabricated using 2D perovskite single-crystal on the rigid Si/SiO2 substrate reveal high photoresponsivity (Rλ)(≈5 A W−1), the fast response time (<20 ms), specific detectivity (D*) (≈3.5 × 1011 Jones), and excellent durability under 488 nm laser illumination. The Rλ and D* values are obtained from the (BA)2FAPb2I77 single-crystal 25 times and three orders magnitudes, respectively, higher than the (BA)2MAPb2I7 single-crystal. Additionally, the perovskite material on flexible polymer substrate reveals good photo-sensing properties in both bending and nonbending states.",

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AU - Lin, Chang‐yu

AU - Subramanian, Ambika

AU - Chen, Wei‐liang

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AU - Rozhin, Alex

AU - Sankar, Raman

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AB - Solution-processable 2D metal-halide perovskites are highly promising for cost-effective optoelectronic applications due to their intrinsic multiquantum well structure. However, the lack of stability is still a major obstacle in the use of this class of materials in practical devices. Here, the authors demonstrate the stable optoelectronic properties using formamidinium (FA)-based centimeter-long 2D perovskite (BA)2FAPb2I7 high-quality single-crystal controlled by the thickness of two perovskite layers. The large area single-crystal exhibits good crystallinity, phase purity, and spectral uniformity. Moreover, the (BA)2FAPb2I7 single-crystal shows excellent stability at open atmospheric conditions when compared to methylammonium (MA)-based (BA)2MAPb2I7 counterparts. The photodetectors fabricated using 2D perovskite single-crystal on the rigid Si/SiO2 substrate reveal high photoresponsivity (Rλ)(≈5 A W−1), the fast response time (<20 ms), specific detectivity (D*) (≈3.5 × 1011 Jones), and excellent durability under 488 nm laser illumination. The Rλ and D* values are obtained from the (BA)2FAPb2I77 single-crystal 25 times and three orders magnitudes, respectively, higher than the (BA)2MAPb2I7 single-crystal. Additionally, the perovskite material on flexible polymer substrate reveals good photo-sensing properties in both bending and nonbending states.

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Stable Formamidinium‐Based Centimeter Long Two‐Dimensional Lead Halide Perovskite Single‐Crystal for Long‐Live Optoelectronic Applications

Abstract

Bibliographical note

Keywords

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