TY - JOUR
T1 - Sustainable Generation of Ni(OH)2 Nanoparticles for the Green Synthesis of 5-Substituted 1 H-Tetrazoles
T2 - A Competent Turn on Fluorescence Sensing of H2O2
AU - Halder, Mita
AU - Islam, Md Mominul
AU - Singh, Pritam
AU - Singha Roy, Anupam
AU - Islam, Sk Manirul
AU - Sen, Kamalika
N1 - This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
PY - 2018/7/31
Y1 - 2018/7/31
N2 - A mutually correlated green protocol has been devised that originates from a sustainable production of β-Ni(OH)2 nanoparticles which is used for an efficient catalytic synthesis of versatile substituted tetrazoles, under mild reaction conditions in water via a simple, one-pot, eco-friendly method. The synthesis is followed by derivatization into a highly fluorescence active compound 9-(4-(5-(quinolin-2-yl)-1H-tetrazol-1-yl)phenyl)-9H-carbazole that can be used at tracer concentrations (0.1 μM) to detect as well as quantify hydrogen peroxide down to 2 μM concentration. The nanocatalyst was synthesized by a simple, proficient, and cost-effective methodology and characterized thoroughly by UV-vis absorption and Fourier transform infrared spectra, N2 adsorption/desorption, high resolution transmission electron microscopy, powder X-ray diffraction pattern, field emission scanning electron microscopy, and thermogravimetric analysis. Broad substrate scope, easy handling, higher efficiency, low cost, and reusability of the catalyst are some of the important features of this heterogeneous catalytic system. The strong analytical performance of the resultant derivative in low-level quantification of potentially hazardous hydrogen peroxide is the key success of the overall green synthesis procedure reported here.
AB - A mutually correlated green protocol has been devised that originates from a sustainable production of β-Ni(OH)2 nanoparticles which is used for an efficient catalytic synthesis of versatile substituted tetrazoles, under mild reaction conditions in water via a simple, one-pot, eco-friendly method. The synthesis is followed by derivatization into a highly fluorescence active compound 9-(4-(5-(quinolin-2-yl)-1H-tetrazol-1-yl)phenyl)-9H-carbazole that can be used at tracer concentrations (0.1 μM) to detect as well as quantify hydrogen peroxide down to 2 μM concentration. The nanocatalyst was synthesized by a simple, proficient, and cost-effective methodology and characterized thoroughly by UV-vis absorption and Fourier transform infrared spectra, N2 adsorption/desorption, high resolution transmission electron microscopy, powder X-ray diffraction pattern, field emission scanning electron microscopy, and thermogravimetric analysis. Broad substrate scope, easy handling, higher efficiency, low cost, and reusability of the catalyst are some of the important features of this heterogeneous catalytic system. The strong analytical performance of the resultant derivative in low-level quantification of potentially hazardous hydrogen peroxide is the key success of the overall green synthesis procedure reported here.
UR - http://www.scopus.com/inward/record.url?scp=85050465271&partnerID=8YFLogxK
U2 - 10.1021/acsomega.8b01081
DO - 10.1021/acsomega.8b01081
M3 - Article
AN - SCOPUS:85050465271
SN - 2470-1343
VL - 3
SP - 8169
EP - 8180
JO - Omega (ACS)
JF - Omega (ACS)
IS - 7
ER -