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The effect of barium substitution on the ferroelectric properties of Sr2 Nb2 O7 Ceramics

  • Zhipeng Gao
  • , Huanpo Ning
  • , Chen Chen
  • , Rory Wilson
  • , Baogui Shi
  • , Haitao Ye
  • , Haixue Yan
  • , Michael J. Reece*
  • *Corresponding author for this work
    • Queen Mary University of London
    • Nanoforce Technology Ltd.

    Research output: Contribution to journalArticlepeer-review

    42   Link opens in a new tab Citations (SciVal)

    Abstract

    This work revealed that the solid solution compounds of Sr 2-xBaxNb2O7 are promising lead-free materials for high-temperature piezoelectric sensor application. These compounds were confirmed as ferroelectric materials with high Curie points (> 900°C) by their piezoelectric activity after poling, ferroelectric domain switching in their P-E hysteresis loops and thermal depoling behavior. The effect of Ba substitution on the structure and properties of Sr 2-xBaxNb2O7 (x < 1.0) was investigated. The solid solution limit of Sr2-xBaxNb 2O7 was determined by XRD as x < 0.6. The a-, b-, c- axes, and cell volume increase with Ba addition. The textured ceramics of Sr2-xBaxNb2O7 were prepared for the first time. The highest d33 was measured as 3.6 ± 0.1 pC/N for Sr1.8Ba0.2Nb2O7.

    Original languageEnglish
    Pages (from-to)1163-1170
    Number of pages8
    JournalJournal of the American Ceramic Society
    Volume96
    Issue number4
    Early online date24 Dec 2012
    DOIs
    Publication statusPublished - Apr 2013

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