The influence of defects on the electron-transfer and magnetic properties of RbxMn[Fe(CN)6]y·zH2O

Esther J.M. Vertelman; Enrico Maccallini; Dimitris Gournis; Petra Rudolf; Thomas Bakas; Javier Luzon; Ria Broer; Andrius Pugzlys; Tom T.A. Lummen; Paul H.M. Van Loosdrecht; Petra J. Van Koningsbruggen

doi:10.1021/cm052521x

The influence of defects on the electron-transfer and magnetic properties of Rb_xMn[Fe(CN)₆]_y·zH₂O

Esther J.M. Vertelman, Enrico Maccallini, Dimitris Gournis, Petra Rudolf, Thomas Bakas, Javier Luzon, Ria Broer, Andrius Pugzlys, Tom T.A. Lummen, Paul H.M. Van Loosdrecht, Petra J. Van Koningsbruggen

Chemical Engineering & Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and detailed characterization of a few samples of the compound RbMn[Fe(CN)]·zHO are described. The composition of the materials significantly depends on the applied preparative conditions. Analysis of spectroscopic results (FTIR, Raman, Fe Mössbauer, XPS) and X-ray powder-diffraction data yielded a further assessment of the difference in structural features in terms of the amount of Fe(CN)6 vacancies and the associated number of water molecules. The characteristic individual magnetic behavior, as well as the metal-to-metal charge-transfer capabilities of the various samples, could be related to significant changes within the structures that appear to be associated with the synthetic method used.

Original language	English
Pages (from-to)	1951-1963
Number of pages	13
Journal	Chemistry of Materials
Volume	18
Issue number	7
DOIs	https://doi.org/10.1021/cm052521x
Publication status	Published - 2 Mar 2006

Access to Document

10.1021/cm052521x

Cite this

@article{7de57b9ddaf646bf8dac6ede57a91a40,

title = "The influence of defects on the electron-transfer and magnetic properties of RbxMn[Fe(CN)6]y·zH2O",

abstract = "The synthesis and detailed characterization of a few samples of the compound RbMn[Fe(CN)]·zHO are described. The composition of the materials significantly depends on the applied preparative conditions. Analysis of spectroscopic results (FTIR, Raman, Fe M{\"o}ssbauer, XPS) and X-ray powder-diffraction data yielded a further assessment of the difference in structural features in terms of the amount of Fe(CN)6 vacancies and the associated number of water molecules. The characteristic individual magnetic behavior, as well as the metal-to-metal charge-transfer capabilities of the various samples, could be related to significant changes within the structures that appear to be associated with the synthetic method used.",

author = "Vertelman, {Esther J.M.} and Enrico Maccallini and Dimitris Gournis and Petra Rudolf and Thomas Bakas and Javier Luzon and Ria Broer and Andrius Pugzlys and Lummen, {Tom T.A.} and {Van Loosdrecht}, {Paul H.M.} and {Van Koningsbruggen}, {Petra J.}",

year = "2006",

month = mar,

day = "2",

doi = "10.1021/cm052521x",

language = "English",

volume = "18",

pages = "1951--1963",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - The influence of defects on the electron-transfer and magnetic properties of RbxMn[Fe(CN)6]y·zH2O

AU - Vertelman, Esther J.M.

AU - Maccallini, Enrico

AU - Gournis, Dimitris

AU - Rudolf, Petra

AU - Bakas, Thomas

AU - Luzon, Javier

AU - Broer, Ria

AU - Pugzlys, Andrius

AU - Lummen, Tom T.A.

AU - Van Loosdrecht, Paul H.M.

AU - Van Koningsbruggen, Petra J.

PY - 2006/3/2

Y1 - 2006/3/2

N2 - The synthesis and detailed characterization of a few samples of the compound RbMn[Fe(CN)]·zHO are described. The composition of the materials significantly depends on the applied preparative conditions. Analysis of spectroscopic results (FTIR, Raman, Fe Mössbauer, XPS) and X-ray powder-diffraction data yielded a further assessment of the difference in structural features in terms of the amount of Fe(CN)6 vacancies and the associated number of water molecules. The characteristic individual magnetic behavior, as well as the metal-to-metal charge-transfer capabilities of the various samples, could be related to significant changes within the structures that appear to be associated with the synthetic method used.

AB - The synthesis and detailed characterization of a few samples of the compound RbMn[Fe(CN)]·zHO are described. The composition of the materials significantly depends on the applied preparative conditions. Analysis of spectroscopic results (FTIR, Raman, Fe Mössbauer, XPS) and X-ray powder-diffraction data yielded a further assessment of the difference in structural features in terms of the amount of Fe(CN)6 vacancies and the associated number of water molecules. The characteristic individual magnetic behavior, as well as the metal-to-metal charge-transfer capabilities of the various samples, could be related to significant changes within the structures that appear to be associated with the synthetic method used.

UR - http://www.scopus.com/inward/record.url?scp=33646093484&partnerID=8YFLogxK

UR - http://pubs.acs.org/doi/abs/10.1021/cm052521x

U2 - 10.1021/cm052521x

DO - 10.1021/cm052521x

M3 - Article

AN - SCOPUS:33646093484

SN - 0897-4756

VL - 18

SP - 1951

EP - 1963

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 7

ER -

The influence of defects on the electron-transfer and magnetic properties of Rb_xMn[Fe(CN)₆]_y·zH₂O

Abstract

Access to Document

Other files and links

Fingerprint

Cite this