The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

Dmitry D. Khalyavin*, Andrei N. Salak, Elena L. Fertman, Oleksandr V. Kotlyar, Edwin Eardley, Nikolai M. Olekhnovich, Anatoli V. Pushkarev, Yury V. Radyush, Alexey V. Fedorchenko, Vladimir A. Desnenko, Pascal Manuel, Lei Ding, Erik Čižmár, Alexander Feher

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

A post-synthesis thermal treatment of metastable phases in the high-pressure stabilised perovskite BiFe1−yScyO3 system results in the irreversible formation of polymorphs which represent novel polar and antipolar structures with interesting magnetic properties. Such annealing-stimulated polymorphism is believed to be a general phenomenon which can be found in other systems.

Original languageEnglish
Pages (from-to)4683-4686
Number of pages4
JournalChemical Communications
Volume55
Issue number32
Early online date26 Mar 2019
DOIs
Publication statusPublished - 16 Apr 2019

Keywords

  • Bismuth/chemistry
  • Iron Compounds/chemistry
  • Magnetic Phenomena
  • Oxides/chemistry
  • Phase Transition
  • Pressure
  • Scandium/chemistry

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    Khalyavin, D. D., Salak, A. N., Fertman, E. L., Kotlyar, O. V., Eardley, E., Olekhnovich, N. M., Pushkarev, A. V., Radyush, Y. V., Fedorchenko, A. V., Desnenko, V. A., Manuel, P., Ding, L., Čižmár, E., & Feher, A. (2019). The phenomenon of conversion polymorphism in Bi-containing metastable perovskites. Chemical Communications, 55(32), 4683-4686. https://doi.org/10.1039/C9CC00472F